119990-10-2Relevant academic research and scientific papers
On the Preparation of Acyl Cyanides from Aldehydes
Haerle, Helmut,Jochims, Johannes C.
, p. 1400 - 1412 (2007/10/02)
The O-silylated cyanohydrins 3 prepared from the aldehydes 1 with trimethylsilyl cyanide are oxidized photochemically or thermally with N-bromosuccinimide to afford the acyl cyanides 4a-n.Scope and limitations of the procedure are discussed.
Substituent Effects on the CC-Bond Strength, 5. Kinetics and Thermochemistry of the Homolytic Dissociation of meso- and D,L-2,3-Dimethoxy-2,3-diphenylsuccinonitrile
Zamkanei, Mohebullah,Kaiser, Juergen H.,Birkhofer, Hermann,Beckhaus, Hans-Dieter,Ruechardt, Christoph
, p. 3216 - 3234 (2007/10/02)
The differences in enthalpy and entropy between meso- and DL-2,3-dimethoxy-2,3-diphenylsuccinonitrile (2) were deduced from the equilibrium constants of their interconversion at elevated temperatures via reversible dissociation into α-cyano-α-methoxybenzy
