13031-13-5Relevant articles and documents
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Boyer,Selvarajan
, p. 47 (1969)
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Nucleophilic Addition of Alkanenitriles to Aldehydes via N -Silyl Ketene Imines Generated in Situ
Yoshimura, Fumihiko,Saito, Hiroki,Abe, Taiki,Tanino, Keiji
supporting information, p. 1816 - 1820 (2017/09/30)
Upon treatment with triisopropylsilyl trifluoromethanesulfonate and 2,2,6,6-tetramethylpiperidine, alkanenitriles undergo direct addition to aldehydes under mild non-basic neutral conditions to provide triisopropylsilyl ethers of β-hydroxy nitriles in goo
DDQ-mediated Direct C(sp3)-H Cyanation of Benzyl Ethers and 1,3-Diarylpropenes under Solvent- and Metal-free Conditions
Kong, Shanshan,Zhang, Lingqiong,Dai, Xiaoli,Tao, Lianzhi,Xie, Chunsong,Shi, Lei,Wang, Min
supporting information, p. 2453 - 2456 (2015/08/18)
A direct cyanation of benzyl ethers and 1,3-diarylpropenes with TMSCN was performed under solvent- and metal-free conditions. This oxidative cross dehydrative coupling (CDC) reaction was promoted by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and provided rapid access to a broad range of nitriles in good to excellent yields.
Reactions of hypervalent iodonium alkynyl triflates with azides: Generation of cyanocarbenes
Hyatt, I. F. Dempsey,Croatt, Mitchell P.
, p. 7511 - 7514 (2012/09/21)
HIAT me, baby, one more time: Cyanocarbenes have been formed by the reaction of azides with hypervalent iodonium alkynyl triflates (HIATs). Experimental evidence supports the potential intermediacy of an azide-substituted vinylidene or alkynyl azide, both of which could form a cyanocarbene. Trapping of the vinylidene and cyanocarbene includes O-H insertion, dimethyl sulfoxide coordination, and cyclopropanation reactions. Copyright