120007-32-1

Basic information

• Product Name: 1-phenylseleno-2-acetamidoheptane
• CAS NO: 120007-32-1
• Molecular Weight: 312.314
• Mol File: 120007-32-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-phenylseleno-2-acetamidoheptane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylseleno-2-acetamidoheptane(120007-32-1)
• EPA Substance Registry System: 1-phenylseleno-2-acetamidoheptane(120007-32-1)

Safety Data

• Hazardous Substances Data: 120007-32-1(Hazardous Substances Data)

Upstream product

• 592-76-7 1-Heptene 
• 22233-89-2 (phenylseleno)-2-propane 
• 110-83-8 cyclohexene 
• 1666-13-3 diphenyl diselenide 
• 75-05-8 acetonitrile 

Relevant articles and documents

Solvent-induced dichotomy in the oxidation mechanism of alkyl aromatic selenoethers

Changing solvent polarity (considered in terms of dielectric permittivity ? is an easy experimental way for tuning the reactivity of electrogenerated cation radicals of alkyl aromatic selenoethers. First-order cleavage of SeC3 bond is favored in polar media, whereas bimolecular cation radical disproportionation becomes the main reaction in low-polar solvents. The key element of this dichotomy is the dielectric adjustment of specific transannular interactions between Se and CO group in the cation radicals. A series of alkyl arylselenides with pending carboxy or acetamido substituents was studied by cyclic voltammetry, IR spectroscopy and DFT calculation in binary solvents covering the span of polarity 8 2Se 2.

ANODIC PHENYLSELENYLATION OF ASYMMETRIC OLEFINS

The anodic phenylselenylation of asymmetric olefins is accompanied by vicinal addition of the active nucleophilic components (water, acetonitrile) at most substituted carbon atoms of the multiple bond.