120017-06-3Relevant academic research and scientific papers
SULFUR-ASSISTED O-CARBONYLATION OF ALCOHOLS WITH CARBON MONOXIDE IN THE PRESENCE OF DBU
Mizuno, Takumi,Nishiguchi, Ikuzo,Hirashima, Tsuneaki,Ogawa, Akiya,Kambe, Nobuaki,Sonoda, Noboru
, p. 4767 - 4768 (1988)
The first example of sulfur-assisted O-carbonylation is described.Alcohols react with carbon monoxide, elemental sulfur, and alkyl halides in the presence of DBU to give S-alkyl carbonothioates selectively in good to excellent yields.
