120041-60-3Relevant academic research and scientific papers
Electrochemical Reductive Smiles Rearrangement for C-N Bond Formation
Chang, Xihao,Zhang, Qinglin,Guo, Chang
, p. 10 - 13 (2019/01/04)
A conceptually new and synthetically valuable radical Smiles rearrangement reaction is reported under undivided electrolytic conditions. This protocol employs an entirely new strategy for the electrochemical radical Smiles rearrangement. Remarkably, an amidyl radical generated from the cleavage of the N-O bond under reductive electrolytic conditions plays a crucial role in this transformation. Various hydroxylamine derivatives bearing different substituents are suitable in this electrochemical transformation, furnishing the corresponding amides in up to 86% yield.
PHOTOCHEMICAL AND THERMAL REACTIONS OF 2-ARYLOXYBENZOHYDROXAMIC ACIDS
Hosangadi, B. D.,Nimbalkar, M. M.,Patel, N. R.
, p. 5857 - 5860 (2007/10/02)
2-Aryloxybenzohydroxamic acids 1-7 were subjected to photolysis in benzene or methanol.In each case corresponding N-arylsalicylamides 8-10 were obtained in good yields.Compounds 1-7 on thermolysis in decaline also produced 8-10.
