120052-51-9

Basic information

• Product Name: (+)-(1S,4R)-4-phenoxy-2-cyclopenten-1-ol
• CAS NO: 120052-51-9
• Molecular Weight: 176.215
• Mol File: 120052-51-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (+)-(1S,4R)-4-phenoxy-2-cyclopenten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(1S,4R)-4-phenoxy-2-cyclopenten-1-ol(120052-51-9)
• EPA Substance Registry System: (+)-(1S,4R)-4-phenoxy-2-cyclopenten-1-ol(120052-51-9)

Safety Data

• Hazardous Substances Data: 120052-51-9(Hazardous Substances Data)

Upstream product

• 7129-41-1 6-oxabicyclo<3.1.0>hex-2-ene 
• 108-95-2 phenol 
• 7129-41-1 6-oxabicyclo[3.1.0]hex-2-ene 
• 542-92-7 cyclopenta-1,3-diene 
• 60410-16-4 (1R,4S)-4-hydroxy-2-cyclopentene-1-yl acetate 
• 108-22-5 Isopropenyl acetate 
• 103056-56-0 (+/-)-cis-4-phenyloxy-2-cyclopenten-1-ol 

Downstream Products

• 169872-81-5 (1S,4R)-cis-1-phenoxy-2-cyclopentene-4-ol 
• 148969-52-2 (-)-(1S,4R)-4-phenyloxy-2-cyclopenten-1-yl acetate 
• 148917-41-3 Acetic acid (3aR,4S,6R,6aS)-2,2-dimethyl-6-phenoxy-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester 
• 210701-09-0 1-acetoxy-4-phenoxy-2-cyclopentene 
• 104010-72-2 (3aS,6aS)-2,2-dimethyl-3a,6a-dihydro-4H-cyclopenta[d][1,3]dioxol-4-one 

Relevant articles and documents

Chemoenzymatic synthesis of a versatile cyclopentenone: (+)-(3aS,6aS)-2,2-dimethyl-3aβ,6aβ-dihydro-4H-cyclopenta-1,3-dioxol- 4-one

The title cyclopentenone has been prepared by enzymatic resolution of cis-4-phenyloxy- and cis-4-(4-methoxyphenyloxy)-cyclopent-2-en-1-ol in isopropenyl acetate using Pseudomonas cepacia lipase. The use of a 4-methoxyphenyloxy-alcohol intermediate enabled the use of both enzymatically resolved enantiomers in the synthesis of the desired (+)-enone.

Enantioselective Preparation of Functionalized Cyclopentanoids via a Common Chiral (?-Allyl)palladium Complex

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