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3-Bromo-5-(Chloromethyl)Pyridine Hydrochloride is a specialized chemical compound characterized by a pyridine ring with a bromine atom at the 3rd position and a chloromethyl group at the 5th position. 3-Bromo-5-(Chloromethyl)Pyridine Hydrochloride is commonly utilized in organic chemistry and pharmaceutical research due to its unique structural properties, which include the presence of a basic aromatic heterocyclic compound similar to benzene but with an additional nitrogen atom. Its reactivity and functional groups make it a valuable reagent in the synthesis of pharmaceuticals and biologically active compounds.

120277-69-2

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120277-69-2 Usage

Uses

Used in Organic Chemistry:
3-Bromo-5-(Chloromethyl)Pyridine Hydrochloride is used as a reagent for the synthesis of various organic compounds due to its reactive bromine and chloromethyl groups, which can participate in a range of chemical reactions, facilitating the creation of diverse molecular structures.
Used in Pharmaceutical Research:
In the pharmaceutical industry, 3-Bromo-5-(Chloromethyl)Pyridine Hydrochloride is used as a building block for the development of new drugs. Its specific structural features allow it to be incorporated into the molecular frameworks of potential therapeutic agents, contributing to the discovery of novel pharmaceuticals with improved efficacy and selectivity.
Used in Synthesis of Biologically Active Compounds:
3-Bromo-5-(Chloromethyl)Pyridine Hydrochloride is utilized as a key intermediate in the synthesis of biologically active compounds, leveraging its chemical reactivity to form new molecules with potential applications in medicine and biology.
Safety Considerations:
Due to its corrosive nature, 3-Bromo-5-(Chloromethyl)Pyridine Hydrochloride can cause burns and serious eye damage. Therefore, it is crucial to handle 3-Bromo-5-(Chloromethyl)Pyridine Hydrochloride with care, using appropriate safety measures such as wearing protective clothing, gloves, and eye protection to minimize the risk of exposure.

Check Digit Verification of cas no

The CAS Registry Mumber 120277-69-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,0,2,7 and 7 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 120277-69:
(8*1)+(7*2)+(6*0)+(5*2)+(4*7)+(3*7)+(2*6)+(1*9)=102
102 % 10 = 2
So 120277-69-2 is a valid CAS Registry Number.
InChI:InChI=1/C6H5BrClN/c7-6-1-5(2-8)3-9-4-6/h1,3-4H,2H2

120277-69-2 Well-known Company Product Price

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  • Alfa Aesar

  • (H66131)  3-Bromo-5-(chloromethyl)pyridine hydrochloride, 96%   

  • 120277-69-2

  • 250mg

  • 564.0CNY

  • Detail
  • Alfa Aesar

  • (H66131)  3-Bromo-5-(chloromethyl)pyridine hydrochloride, 96%   

  • 120277-69-2

  • 1g

  • 1695.0CNY

  • Detail
  • Alfa Aesar

  • (H66131)  3-Bromo-5-(chloromethyl)pyridine hydrochloride, 96%   

  • 120277-69-2

  • 5g

  • 6772.0CNY

  • Detail

120277-69-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Bromo-5-(chloromethyl)pyridine

1.2 Other means of identification

Product number -
Other names BH399

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:120277-69-2 SDS

120277-69-2Relevant academic research and scientific papers

Discovery of 3-Pyridyl Isoindolin-1-one Derivatives as Potent, Selective, and Orally Active Aldosterone Synthase (CYP11B2) Inhibitors

Liu, Yongfu,Wu, Jun,Zhou, Mingwei,Chen, Wenming,Li, Dongbo,Wang, Zhanguo,Hornsperger, Benoit,Aebi, Johannes D.,M?rki, Hans-Peter,Kuhn, Bernd,Wang, Lisha,Kuglstatter, Andreas,Benz, J?rg,Müller, Stephan,Hochstrasser, Remo,Ottaviani, Giorgio,Xin, Jian,Kirchner, Stephan,Mohr, Susanne,Verry, Philippe,Riboulet, William,Shen, Hong C.,Mayweg, Alexander V.,Amrein, Kurt,Tan, Xuefei

supporting information, p. 6876 - 6897 (2020/08/14)

Aldosterone synthase (CYP11B2) inhibitors have been explored in recent years as an alternative therapeutic option to mineralocorticoid receptor (MR) antagonists to reduce elevated aldosterone levels, which are associated with deleterious effects on various organ systems including the heart, vasculature, kidney, and central nervous system (CNS). A benzamide pyridine hit derived from a focused screen was successfully developed into a series of potent and selective 3-pyridyl isoindolin-1-ones CYP11B2 inhibitors. Our systematic structure-activity relationship study enabled us to identify unique structural features that result in high selectivity against the closely homologous cortisol synthase (CYP11B1). We evaluated advanced lead molecules, exemplified by compound 52, in an in vivo cynomolgus monkey acute adrenocorticotropic hormone (ACTH) challenge model and demonstrated a superior 100-fold in vivo selectivity against CYP11B1.

Novel 2,4-disubstituted pyrimidines as potent, selective, and cell-permeable inhibitors of neuronal nitric oxide synthase

Mukherjee, Paramita,Li, Huiying,Sevrioukova, Irina,Chreifi, Georges,Martásek, Pavel,Roman, Linda J.,Poulos, Thomas L.,Silverman, Richard B.

, p. 1067 - 1088 (2015/03/04)

Selective inhibition of neuronal nitric oxide synthase (nNOS) is an important therapeutic approach to target neurodegenerative disorders. However, the majority of the nNOS inhibitors developed are arginine mimetics and, therefore, suffer from poor bioavai

DIHYDROQUINOLINE-2-ONE DERIVATIVES FOR USE AS ALDOSTERONE SYNTHASE INHIBITORS

-

Page/Page column 25, (2014/09/29)

The invention provides novel compounds having the general formula (I) wherein R1, R2, R3, R4, R5, R6, R7, R9, R10 and R11 are as described herein, compositions including the compounds and methods of using the compounds.

DIHYDROQUINOLINE-2-ONE DERIVATIVES

-

Paragraph 0586; 0587, (2013/03/28)

The invention provides novel compounds having the general formula (I) wherein R1, R2, R3, R4, R5, R6, R7, A1, A2 and A3 are as described herein, compositions including the compounds and methods of using the compounds. These compounds are useful for therapy or prophylaxis in a mammal, and in particular as aldosterone synthase (CYP11B2 or CYP11B1) inhibitors for the treatment or prophylaxis of chronic kidney disease, congestive heart failure, hypertension, primary aldosteronism and Cushing syndrome.

NEW DIHYDROQUINOLINE-2-ONE DERIVATIVES

-

Page/Page column 84; 85, (2013/03/28)

The invention provides novel compounds having the general formula (I) wherein R1, R2, R3, R4? R5, R6, R7, A1, A2 and A3 are as described herein, compositions including the compounds and methods of using the compounds.

NEW BICYCLIC DIHYDROISOQUINOLINE-1-ONE DERIVATIVES

-

Page/Page column 173, (2013/06/27)

The invention provides novel compounds having the general formula (I) wherein R1, R2, R3, R4? R5, R6, A1, A2, A3, A4, A5 and n are as described herein,compositions including the compounds and methods of using the compounds as aldosterone synthase (CYP11B2 or CYP11B1) inhibitors for the treatment or prophylaxis of chronic kidney disease, congestive heart failure, hypertension, primary aldosteronism and Cushing syndrom.

NEW BICYCLIC DIHYDROISOQUINOLINE-1-ONE DERIVATIVES

-

Paragraph 1244, (2013/06/26)

The invention provides novel compounds having the general formula (I) wherein R1, R2, R3, R4, R5, R6, A1, A2, A3, A4, A5 and n are as

Design and synthesis of active site inhibitors of the human farnesyl pyrophosphate synthase: Apoptosis and inhibition of ERK phosphorylation in multiple myeloma cells

Lin, Yih-Shyan,Park, Jaeok,De Schutter, Joris W.,Huang, Xian Fang,Berghuis, Albert M.,Sebag, Michael,Tsantrizos, Youla S.

experimental part, p. 3201 - 3215 (2012/05/20)

Human farnesyl pyrophosphate synthase (hFPPS) controls intracellular levels of FPP and post-translational prenylation of small GTPase proteins, which are essential for cell signaling and cell proliferation. Clinical investigations provide evidence that N-BP inhibitors of hFPPS are disease modifying agents that improve survival of multiple myeloma (MM) patients via mechanisms unrelated to their skeletal effects. A new series of N-BPs was designed that interact with a larger portion of the GPP subpocket, as compared to the current therapeutic drugs, and rigidify the 364KRRK367 tail of hFPPS in the closed conformation in the absence of IPP. An analogue of this series was used to demonstrate inhibition of the intended biological target, resulting in apoptosis and down-regulation of ERK phosphorylation in human MM cell lines.

QUINAZOLINES AS POTASSIUM ION CHANNEL INHIBITORS

-

Page/Page column 287, (2011/04/14)

A compound of formula (I) wherein A, X, Y, Z, R1 and R24 are described herein. The compounds are useful as inhibitors of potassium channel function and in the treatment and prevention of arrhythmia, IKur-associated disorders, and other disorders mediated by ion channel function.

Imidazole derivatives

-

, (2008/06/13)

Novel imidazole derivatives are disclosed. These compounds have a good affinity to the NMDA (N-methyl-D-aspartate)-receptor subtype selective blockers, which have a key function in modulating neuronal activity and plasticity which makes them key players in mediating processes underlying development of CNS as well as learning and memory formation. These compounds are useful in the control or treatment of diseases mediated by this receptor.

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