120329-65-9Relevant academic research and scientific papers
Enantioselective Hydroformylation of 1-Alkenes with Commercial Ph-BPE Ligand
Yu, Zhiyong,Eno, Meredith S.,Annis, Alexandra H.,Morken, James P.
, p. 3264 - 3267 (2015/07/15)
A rhodium complex, in conjunction with commercially available Ph-BPE ligand, catalyzes the branch-selective asymmetric hydroformylation of 1-alkenes and rapidly generates α-chiral aldehydes. A wide range of terminal olefins including 1-dodecene were examined, and all delivered high enantioselectivity (up to 98:2 er) as well as good branch:linear ratios (up to 15:1). (Chemical Equation Presented).
Nef-Perkow access to indolizine derivatives
Coffinier, Didier,Elkaim, Laurent,Grimaud, Laurence
scheme or table, p. 2474 - 2476 (2010/11/18)
We present herein a new access to indolizine derivatives involving 1,3-dipolar cycloaddition of pyridinium ylides with phosphorylated hydroxyketenimines. These ketenimines are easily formed via a Nef-Perkow cascade involving isocyanides as starting material. Georg Thieme Verlag Stuttgart · New York.
