120329-89-7

Upstream product

• 24074-26-8 ethyl (diisopropylphosphoryl)acetate 
• 87256-56-2 (2R,3S)-3-Benzyloxy-2-methoxy-3-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-propionaldehyde 
• 87256-58-4 3-O-benzyl-6-deoxy-2-O-methyl-D-galactose diethyldithioacetal 
• 73472-26-1 (2R,3S)-3-Methyl-1,4-dioxa-spiro[4.5]decane-2-carboxylic acid methyl ester 
• 80952-63-2 (2R,3S)-2,3-(cyclohexylidenedioxy)butanol 
• 120264-67-7 (2S,3R)-2-((1S,2R)-1-Benzyloxy-3,3-bis-ethylsulfanyl-2-methoxy-propyl)-3-methyl-1,4-dioxa-spiro[4.5]decane 
• 100-39-0 benzyl bromide 
• 73111-71-4 (3aR,4S,6R,7R,7aR)-4-Bromomethyl-6-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 71748-62-4 2-O-Methyl-methyl-β-D-fucopyranosid 
• 120264-45-1 (2S,3R)-2-((1R,2S)-1-Benzyloxy-2-methoxy-but-3-enyl)-3-methyl-1,4-dioxa-spiro[4.5]decane 
• 87256-55-1 D-Galacto-3-methoxyhept-1-ene-4,5,6-triol 5,6-cyclohexyl ketal 
• 87305-35-9 L-4-deoxythreose cyclohexyl ketal 
• 71695-47-1 (3aS,4R,6R,7R,7aS)-6,7-Dimethoxy-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 

Downstream Products

• 87357-96-8 (S)-3-[(1S,2R)-2-Benzyloxy-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-pent-4-enoic acid ethyl ester 
• 87357-96-8 (R)-3-[(1S,2R)-2-Benzyloxy-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-pent-4-enoic acid ethyl ester 
• 87357-98-0 (Z)-(S)-3-[(1S,2R)-2-Benzyloxy-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-hex-4-enoic acid ethyl ester 
• 87357-98-0 (Z)-(R)-3-[(1S,2R)-2-Benzyloxy-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-hex-4-enoic acid ethyl ester 

Relevant academic research and scientific papers

A highly stereoselective synthesis of (+)-olivin, the aglycon of olivomycin A

The first total synthesis of (+)-olivin (1), the naturally occurring enantiomer of the aglycon of olivomycin A, is described. The synthesis is highly stereoselective, featuring the reaction of (γ-methoxyallyl)boronate 21 with chiral aldehyde 17 and the ad

Studies on the Synthesis of Olivin: Diastereoselective Synthesis of a Functionalized D-Fucose Derivative

A short, highly diastereoselective synthesis of D-fucose derivative 4 by a route involving the addition of allylboronate reagent 7 to aldehyde 6 is described.