24074-26-8

Basic information

• Product Name: DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE
• Synonyms: DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE;Ethyl (diisopropyl phosphono)acetate
• CAS NO: 24074-26-8
• Molecular Formula: C₁₀H₂₁O₅P
• Molecular Weight: 252.24
• Product Categories: C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
• Mol File: 24074-26-8.mol
• Article Data: 0

Chemical Properties

• Boiling Point: 142-143 °C11 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.06 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.00472mmHg at 25°C
• Refractive Index: n20/D 1.427(lit.)
• CAS DataBase Reference: DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE(24074-26-8)
• EPA Substance Registry System: DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE(24074-26-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 24074-26-8(Hazardous Substances Data)

Usage

Uses

Reactant for:Preparation of spiroimine ring fragment of spirolides via stereoselective intermolecular Diels-Alder and aza-Wittig cyclizationKatsuki-Sharpless epoxidation reactionPreparation of nine-membered diallylic sulfonamides as chiral building blocksAlpha-phosphono lactams for subsequent Wadsworth-Emmons olefination, and Suzuki coupling reactions to yield diverse pyrrolidinone compoundsSynthesis of galactosylceramide analog that induces Th1-biased responses in human (NKT) cellsStereoselective total synthesis of the ionophore antibiotic zincophorin (M144255)

InChI:InChI=1/C10H21O5P/c1-6-13-10(11)7-16(12,14-8(2)3)15-9(4)5/h8-9H,6-7H2,1-5H3

Upstream product

• 116-17-6 triisopropyl phosphite 
• 105-39-5 chloroacetic acid ethyl ester 
• 59374-81-1 (chloro-isopropoxy-phosphoryl)-acetic acid ethyl ester 
• 67-63-0 isopropyl alcohol 
• 105-36-2 ethyl bromoacetate 
• 42451-44-5 (2-chloro-2-ethoxy-vinyl)-phosphonic acid dichloride 

Downstream Products

• 64520-58-7 ethyl (E)-3-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate 
• 135251-95-5 (2E)-ethyl 2-hexadecenoate 
• 1430811-68-9 (E)-ethyl 3-[(R)-2-(4-octylphenethyl)oxiran-2-yl]acrylate 
• 917871-10-4 (R)-(E)-(+)-ethyl-5-(tert-butyldiphenylsilyloxy)-4-methyl-2-pentenoate 
• 1256293-16-9 ethyl 2-(diisopropoxyphosphoryl)-6-(p-methoxybenzyloxy)hexanoate 
• 600153-20-6 C₁₇H₂₃NO₄S 
• 40032-55-1 N-cinnamylbenzylamine 
• 950782-94-2 (3R,4S,5S)-diisopropyl (1,5-dimethyl-2-oxo-4-phenylpyrrolidin-3-yl)phosphonate 
• 889893-54-3 ethyl (S,E)-3-[4-(tert-butyldimethylsiloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl]acrylate 
• 889893-49-6 ethyl (R,E)-3-(4-acetoxymethyl-2-phenyl-4,5-dihydrooxazol-4-yl)acrylate 
• 55282-95-6 ethyl (2E)-5-phenylpent-2-enoate 
• 609355-72-8 (E)-(4R,6R)-4,8-Bis-benzyloxy-6-methyl-oct-2-enoic acid ethyl ester 
• 536737-82-3 ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate 
• 181996-97-4 (S)-N-[[3-[3-fluoro-4-[3-(2-carbethoxyvinyl)-1H-pyrrol-1-yl]phenyl]-2-oxo-5-oxazolidinyl]methyl]acetamide