120342-68-9Relevant articles and documents
Chemoselective, Isomerization-Free Synthesis of N-Acylketimines from N–H Imines
Kwon, Yearang,Rhee, Young Ho,Park, Jaiwook
supporting information, p. 1503 - 1507 (2017/05/05)
N-Acylketimines were synthesized through a ruthenium-catalyzed generation of N–H ketimines from secondary azides and subsequent acylation with mixed anhydrides under mild conditions. The synthetic scope was broad to give N-acylimines having various functi
Selective Conversion of Benzylic C-H Bonds to an Amine Function by Oxidative Nucleophilic Substitution
Guy, Alain,Lemor, Alain,Doussot, Joel,Lemaire, Marc
, p. 900 - 902 (2007/10/02)
The benzylic proton of alkylarenes 1 was replaced by an azido group in one step by reaction with trimethylsilyl azide or hydrazoic acid in chloroform in the presence of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ).The 1-arylalkyl azides 2 were reduced to amines 3, which were characterized as their hydrochlorides 4.