120342-68-9Relevant academic research and scientific papers
Chemoselective, Isomerization-Free Synthesis of N-Acylketimines from N–H Imines
Kwon, Yearang,Rhee, Young Ho,Park, Jaiwook
supporting information, p. 1503 - 1507 (2017/05/05)
N-Acylketimines were synthesized through a ruthenium-catalyzed generation of N–H ketimines from secondary azides and subsequent acylation with mixed anhydrides under mild conditions. The synthetic scope was broad to give N-acylimines having various functi
Exploiting the Nucleophilicity of N-H Imines: Synthesis of Enamides from Alkyl Azides and Acid Anhydrides
Han, Junghoon,Jeon, Mina,Pak, Han Kyu,Rhee, Young Ho,Park, Jaiwook
supporting information, p. 2769 - 2774 (2016/02/18)
The nucleophilicity of N-unsubstituted imines, which were generated from alkyl azides by a ruthenium-catalyzed reaction, was investigated in the reaction with acid anhydrides. The initial products were N-acylimines, which isomerized to the corresponding e
Selective Conversion of Benzylic C-H Bonds to an Amine Function by Oxidative Nucleophilic Substitution
Guy, Alain,Lemor, Alain,Doussot, Joel,Lemaire, Marc
, p. 900 - 902 (2007/10/02)
The benzylic proton of alkylarenes 1 was replaced by an azido group in one step by reaction with trimethylsilyl azide or hydrazoic acid in chloroform in the presence of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ).The 1-arylalkyl azides 2 were reduced to amines 3, which were characterized as their hydrochlorides 4.
