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1203709-76-5

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  • (3-BroMophenyl)(2,4,6-triMethylphenyl)iodoniuM triflate

    Cas No: 1203709-76-5

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1203709-76-5 Usage

General Description

The chemical compound "(3-Bromophenyl)(2,4,6-trimethylphenyl)iodonium triflate" is a complex organic salt that contains a combination of three different chemical groups: a bromophenyl group, a 2,4,6-trimethylphenyl group, and an iodonium triflate group. The compound is used as a reagent in organic synthesis, particularly in the process of transferring the bromophenyl or trimethylphenyl group to other organic molecules. It is commonly utilized in chemical reactions to create new carbon-carbon and carbon-heteroatom bonds. Due to its specific molecular structure and reactivity, it has applications in the production of pharmaceuticals, agrochemicals, and materials science. Additionally, it is considered an important tool in the field of organic chemistry for the formation of complex organic molecules.

Check Digit Verification of cas no

The CAS Registry Mumber 1203709-76-5 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,0,3,7,0 and 9 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1203709-76:
(9*1)+(8*2)+(7*0)+(6*3)+(5*7)+(4*0)+(3*9)+(2*7)+(1*6)=125
125 % 10 = 5
So 1203709-76-5 is a valid CAS Registry Number.

1203709-76-5 Well-known Company Product Price

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  • Aldrich

  • (743747)  (3-Bromophenyl)(2,4,6-trimethylphenyl)iodonium triflate  ≥95%

  • 1203709-76-5

  • 743747-1G

  • 2,454.66CNY

  • Detail
  • Aldrich

  • (743747)  (3-Bromophenyl)(2,4,6-trimethylphenyl)iodonium triflate  ≥95%

  • 1203709-76-5

  • 743747-5G

  • 9,835.02CNY

  • Detail

1203709-76-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (3-bromophenyl)-(2,4,6-trimethylphenyl)iodanium,trifluoromethanesulfonate

1.2 Other means of identification

Product number -
Other names (3-Bromophenyl)(2,4,6-trimethylphenyl)iodonium triflate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1203709-76-5 SDS

1203709-76-5Relevant articles and documents

Catalyst-Free Arylation of Tertiary Phosphines with Diaryliodonium Salts Enabled by Visible Light

Bugaenko, Dmitry I.,Volkov, Alexey A.,Livantsov, Mikhail V.,Yurovskaya, Marina A.,Karchava, Alexander V.

supporting information, p. 12502 - 12506 (2019/09/16)

The visible-light-induced arylation of tertiary phosphines with aryl(mesityl)iodonium triflates to produce the quaternary phosphonium salts occurs under mild, metal, and catalyst-free conditions. Photo-excited EDA complexes between diaryliodonium salts an

Copper-catalyzed oxidative ring closure of ortho-cyanoanilides with hypervalent iodonium salts: Arylation-ring closure approach to iminobenzoxazines

Aradi, Klra,Novk, Zoltn

supporting information, p. 371 - 376 (2015/03/05)

A novel, highly modular synthetic methodology with high functional group tolerance was developed for the construction of iminobenzoxazine derivatives from ortho-cyanoanilides and diaryliodonium triflates via an oxidative arylation-cyclization path. The reaction is supposed to involve the formation of highly active aryl-copper(III) species. In this novel transformation, copper(II) triflate was used as catalyst in 1,2-dichloroethane or ethyl acetate and the reaction takes place at 75 °C in 2-16 h.

Utilization of Copper-Catalyzed Carboarylation-Ring Closure for the Synthesis of New Oxazoline Derivatives

Sinai, ádám,Vangel, Dóra,Gáti, Tamás,Bombicz, Petra,Novák, Zoltán

supporting information, p. 4136 - 4139 (2015/09/15)

A copper-catalyzed carboarylation-ring-closure strategy was used for the modular synthesis of oxazolines via the reaction of 1-aryl- and 1-alkylpropargylamides and diaryliodonium salts. The novel approach enables the efficient, modular synthesis of oxazol

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