120384-06-7Relevant academic research and scientific papers
The role of the α-stereogenic center in the control of stereoselection in the reduction of α-alkyl-β-hydroxy ketones: A highly diastereoselective protocol for the synthesis of 1,2-syn-2-alkyl-1,3-diols
Bartoli, Giuseppe,Bellucci, Maria C.,Bosco, Marcella,Dalpozzo, Renato,Marcantoni, Enrico,Sambri, Letizia
, p. 2590 - 2598 (2007/10/03)
Accurate investigations on the role played by an α-stereogenic center in controlling the reduction of various classes of β-hydroxy ketones allowed us to set up a general and highly diastereoselective protocol for the synthesis of 2-alkyl-1,3-diols with 1,
ADDITION OF α-CHLOROBENZYL BENZOATE TO ALKENES
Borodaev, S. V.,Luk'yanov, S. M.
, p. 1259 - 1264 (2007/10/02)
In the presence of zinc chloride α-chlorobenzyl benzoate adds to alkenes with high diastereoselectivity, forming 1,3-dioxanium chlorozincates and γ-chloroesters.The products are easily transformed into 1,3-diols with a branched carbon skeleton.
