120417-03-0Relevant articles and documents
USE OF 1JC1,H1 VALUES FOR THE STEREOCHEMICAL DETERMINATION OF C-GLYCOSIDES: A SIMPLE TWO DIMENSIONAL NMR PROTOCOL
Sparks, Michelle A.,Panek, James S.
, p. 407 - 410 (2007/10/02)
A combination of three two-dimensional homo- and heteronuclear correlation methods have been used to determine the stereochemistry of C-glycosides derived from the reaction of 1-acetyloxy allylic silanes with pyranosi
Oxygenated Allylic Silanes: Useful Homoenolate Equivalents for the Stereoselective C-Glycosidation of Pyranoside Derivatives
Panek, James S.,Sparks, Michelle A.
, p. 2034 - 2038 (2007/10/02)
Acylated C1-oxygenated allylic silanes, trimethylsilane (1a), trimethylsilane (1b), and ethyl 2-propenyltrimethylsilane-1-carbonate (1c), function as homoenolate equivalents in BF3*OEt2-catalyze