96689-97-3

Upstream product

• 120417-03-0 Acetic acid (E)-3-((3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-propenyl ester 
• 136088-95-4 1-(2,3,4,6-O-tetrabenzyl-β-D-glucopyranosyl)-2,3-propanediol 
• 81972-19-2 1-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-2-propene 
• 82614-10-6 ethyl 2-((2S,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)acetate 
• 4196-36-5 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl 4-nitrobenzoate 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 6213-94-1 trimethylsiloxyethene 
• 74352-41-3 2-Pyridyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 
• 81972-19-2 α-allyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 123043-08-3 (2R,3S,4S,5R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-2,3,4,5-tetrahydro-pyranylium 
• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 120520-77-6 2-{(2R,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl] tetrahydro-2H-pyran-2-yl}acetaldehyde 
• 120417-03-0 Acetic acid (E)-3-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-propenyl ester 

Downstream Products

• 452068-70-1 2-(2',3',4',6'-tetra-O-benzyl-β-D-glucopyranosyl)-1-iodoethane 
• 477247-01-1 (3R,5R,6S)-3-(2'-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)ethyl)-4-(t-butoxycarbonyl)-5,6-diphenyl-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one 
• 1217514-15-2 (E)-4-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-1-(thiazol-2-yl)-but-2-en-1-one 
• 96689-97-3 (2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanal 
• 87256-53-9 (S)-5-[(1S,2R,3R)-1,2-Dihydroxy-3-methyl-4-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butyl]-dihydro-furan-2-one 
• 83861-86-3 (S)-1-{(4S,5R)-2,2-Dimethyl-5-[(R)-1-methyl-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl]-[1,3]dioxolan-4-yl}-pent-4-en-1-ol 
• 87263-31-8 (2R,3R)-1-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-4-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butan-2-ol 
• 87256-51-7 [(2R,3R)-3-((2S,3R,4S,5S,6S)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl)-oxiranyl]-methanol 
• 87256-50-6 4-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranos-1-yl)-but-2-en-1-ol 
• 87256-54-0 (S)-1-((2R,3aR,5R,6R,7S,7aS)-6,7-Bis-benzyloxy-5-benzyloxymethyl-hexahydro-furo[3,2-b]pyran-2-yl)-ethane-1,2-diol 

Relevant academic research and scientific papers

Synthesis of new C-glycosyl aza-β3-amino acids building blocks

New C-glycosylated Nβ-protected aza-β3- amino acid building blocks have been prepared from C-glycosyl aldehydes of gluco and galacto configuration by reductive amination and subsequent N-alkylation. These moieties were elaborated to

An approach to stereoselective preparation of 3-C-glycosylated d- and l-glucals

An approach to stereoselective synthesis of α- or β-3-C-glycosylated l- or d-1,2-glucals starting from the corresponding α- or β-glycopyranosylethanals is described. The key step of the approach is the stereoselective cycloaddition of chiral vinyl ethers

General synthesis of C-glycosyl amino acids via proline-catalyzed direct electrophilic α-amination of C-glycosylalkyl aldehydes

(Chemical Equation Presented) Non-natural axially and equatorially linked C-glycosyl α-amino acids (glycines, alanines, and CH2-serine isosteres) with either S or R α-configuration were prepared by D- and L-proline-catalyzed (de >95%) α-aminati

Microwave-assisted organocatalytic anomerization of α-C- glycosylmethyl aldehydes and ketones

(Chemical Equation Presented) The use of L-proline (30 mol %) and MW irradiation (13 W) with cooling promotes in a few hours the almost quantitative anomerization of α-C-glycosylmethyl aldehydes into β-isomers. An open-chain enamine-based mechanism is pos

Synthesis and partial biological evaluation of a small library of differentially-linked β-C-disaccharides

The synthesis of a small library of differentially-linked β-C-disaccharides has been carried out through the use of a radical allylation-RCM strategy. Acids 6 were prepared by Keck allylation of a suitable carbohydrate-based radical precursor, followed by

A novel general route for the synthesis of C-glycosyl tyrosine analogues.

A general method for the synthesis of C-glycosyl amino acids is described here. The stereoisomerically pure tyrosine analogues alpha-L-4 and beta-L-6 are prepared in reasonable overall yields from allyl derivatives 10 and 11. The key step is a benzannulation procedure which is employed in the creation of the aromatic ring that bears the amino acid function.

A general strategy for the convergent synthesis of fused polycyclic ethers via B-alkyl Suzuki coupling: Synthesis of the ABCD ring fragment of ciguatoxins

A new method for convergent coupling of fused polycyclic ethers has been developed, which relies on B-alkyl Suzuki crosscoupling of lactone-derived enol triflates or phosphates. The strategy was successfully applied to a convergent synthesis of the ABCD r

Synthesis of C-linked glycopyranosyl serines via a chiral glycine enolate equivalent.

[formula: see text] The stereoselective preparation of C-linked D-gluco- and D-galactopyranosyl L-serines in their alpha and beta forms is herein reported. The syntheses require the conversion of the allyl C-glycopyranosides into their iodoethyl derivativ

Preferred Conformation of C-Glycosides. 7. Preferred Conformation of Carbon Analogues of Isomaltose and Gentiobiose

The preferred solution conformation of the 1,6-linked C-disaccharides 3 and 4, carbon analogues of methyl isomaltoside and methyl gentiobioside, was shown to be 3-A and 4-A, respectively, by 1H NMR spectroscopy.

USE OF 1JC1,H1 VALUES FOR THE STEREOCHEMICAL DETERMINATION OF C-GLYCOSIDES: A SIMPLE TWO DIMENSIONAL NMR PROTOCOL

A combination of three two-dimensional homo- and heteronuclear correlation methods have been used to determine the stereochemistry of C-glycosides derived from the reaction of 1-acetyloxy allylic silanes with pyranosi