120417-92-7

Upstream product

• 41670-98-8 1-((3aR,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethanone 
• 762-72-1 allyl-trimethyl-silane 
• 120417-91-6 <3aR(3aα,6β,6aα)>-tetrahydro-2,2-dimethyl-5-acetoxy-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 39682-04-7 (3aR,5S,6R,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuran[2,3-d][1,3]dioxolane-5-carboxylic acid 

Downstream Products

• 120520-95-8 (2S,3S,4R)-3-(phenylmethoxy)-6-heptene-1,2,4-triol 
• 120418-02-2 (2S,3S,4S)-3-(phenylmethoxy)-6-heptene-1,2,4-triol 
• 111555-40-9 (4S)-4-<(1S,2R)-1-(phenylmethoxy)-2-(benzoyloxy)-4-penten-1-yl>-2,2-dimethyl-1,3-dioxole 
• 111462-27-2 (1S,2R)-1-(benzyloxy)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)pent-4-en-2-ol 

Relevant academic research and scientific papers

New Chirons from D-Glucose. Regio- and Diastereoselective C-C Bond Forming Reactions Exploiting Novel Aldotetrafuranose Acetates as Chiral Synthetic Equivalents of Tartaric Aldehydes

Two differentially protected tetrafuranose acetates 5 and 6 have been prepared from diacetone D-glucose in parallel short routes.They clearly act as chiral synthetic equivalents of D- and meso-tartaric aldehydes when exploited in Lewis acid promoted react

NOVEL SYNTHETIC EQUIVALENTS OF DIFFERENTIALLY PROTECTED TARTARIC ALDEHYDES. A SIMPLE ROUTE TO USEFUL C-4 CHIRAL SYNTHONS.

The synthesis of 4-acetoxy-3-O-benzyl-1,2-O-isopropylidene aldotetroses from D-glucose is reported.These synthetic equivalents of tartaric aldehydes are chemoselectively reduced at the acetoxylated center leading to a series of useful differentially protected C-4 chiral synthons.