39682-04-7

Upstream product

• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 34370-91-7 3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 
• 101475-83-6 3-O-benzyl-1,2;5,6-di-O-isopropylidene-α-D-glucofuranoside 
• 582-52-5 1,2:5,6-diacetone-D-glucose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 50-99-7 D-glucose 
• 908142-25-6 1-2 O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose 
• 591727-19-4 1-2,5-6 di-O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose 
• 100-39-0 benzyl bromide 
• 350255-13-9 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 39682-05-8 (4S)-O³-benzyl-O¹,O²-isopropylidene-4-(5-phenyl-[1,3,4]oxadiazol-2-yl)-β-L-threofuranose 
• 163627-97-2 methyl (methyl-3-O-benzyl-α-D-xylofuranoside) uronate 
• 88151-65-9 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-6-C--α-D-xylo-hexofuranos-5-ulose 
• 140138-21-2 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-6-C--α-D-glucofuranose 
• 121360-03-0 3-O-benzyl-1,2-O-isopropylidene-6-C--L-glycero-α-D-gluco-hexofuranose 
• 140138-25-6 3-O-benzyl-1,2-O-isopropylidene-6-C--α-D-gluco-hexofuranos-5-ulose 
• 140138-25-6 3-O-benzyl-1,2-O-isopropylidene-6-C--β-L-ido-hexofuranos-5-ulose 
• 1599474-01-7 (S)-benzyl 2-(((3aR,5S,6R,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole-5-carboxamido)methyl)pyrrolidine-1-carboxylate 
• 1227850-52-3 (1H-benzo[d][1,2,3]triazol-1-yl)(6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methanone 
• 89755-56-6 <3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole 
• 120417-92-7 (3aR,5S,6S,6aR)-5-Allyl-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 76768-64-4 (3aR,6S,6aR)-6-(benzyloxy)-tetrahydro-2,2-dimethylfuro[2,3-d][1,3]dioxole 
• 121701-09-5 (2S,3R)-2-benzyloxy-pent-4-ene-1,3-diol 
• 121611-66-3 (3R,4S)-4-Benzyloxy-tetrahydro-furan-2,3-diol 

Relevant academic research and scientific papers

Method for synthesizing release type xylose ester perfume for tobacco perfuming

A synthesis method of a release type xylose ester spice for flavoring tobacco is provided. The glucose is used as a raw material, the principle of esterifying carboxylic acid and alcohol to prepare ester is adopted, a common parent carboxylic acid which c

Visible-Light-Mediated, Chemo- and Stereoselective Radical Process for the Synthesis of C-Glycoamino Acids

An approach for efficient synthesis of C-glycosyl amino acids is described. Different from typical photoredox-catalyzed reactions of imines, the new process follows a pathway in which α-imino esters serve as electrophiles in chemoselective addition reactions with nucleophilic glycosyl radicals. The process is highlighted by the mild nature of the reaction conditions, the highly stereoselectivity attending C-C bond formation, and its applicability to C-glycosylations using both armed and disarmed pentose and hexose derivatives.

I2/PPh3-mediated facile synthesis of glycoconjugated N-acylbenzotriazoles

A well-stabilized method for synthesis of N-acylbenzotriazoles from carboxylic acids using I2/PPh3 in anhydrous dichloromethane has been extended in glycochemistry to synthesize glycoconjugated N-acylbenzotriazoles with high yields at room temperature in 2-hour reaction time.

Stereoselective synthesis of spiro-β-lactams using d-(+)-glucose derived chiral pool: remarkable influence of the torquoelectronic effect

Diastereoselective synthesis of spiro-β-lactams via [2+2] cycloaddition reaction of imines and chiral ketenes is described. The chiral ketene was prepared from commercially available, inexpensive d-glucose. Although, theoretically four diastereomers are p

Short Synthetic Route to Congeners of the Undecose Antibiotic Herbicidin

The undecose backbone of the herbicidins has been assemled via direct alkylation, hydroxyalkylation, or acylation of the cyclic vinylanion 5 with the xylofuranose triflate 14, aldehyde 6, or acid chloride 10, respectively.

Peparation of higher-carbon sugars by stereoselective osmylation of related allylic alcohols

The catalytic osmylation of the following higher-carbon sugar allylic alcohols and enones was examined. 3-O-Benzyl-5-deoxy-5-C--1,2-O-isopropylidene-α-D-xylofuranose (5) af

New Chirons from D-Glucose. Regio- and Diastereoselective C-C Bond Forming Reactions Exploiting Novel Aldotetrafuranose Acetates as Chiral Synthetic Equivalents of Tartaric Aldehydes

Two differentially protected tetrafuranose acetates 5 and 6 have been prepared from diacetone D-glucose in parallel short routes.They clearly act as chiral synthetic equivalents of D- and meso-tartaric aldehydes when exploited in Lewis acid promoted react

NOVEL SYNTHETIC EQUIVALENTS OF DIFFERENTIALLY PROTECTED TARTARIC ALDEHYDES. A SIMPLE ROUTE TO USEFUL C-4 CHIRAL SYNTHONS.

The synthesis of 4-acetoxy-3-O-benzyl-1,2-O-isopropylidene aldotetroses from D-glucose is reported.These synthetic equivalents of tartaric aldehydes are chemoselectively reduced at the acetoxylated center leading to a series of useful differentially protected C-4 chiral synthons.