111462-27-2

Upstream product

• 120418-02-2 (2S,3R,4R)-3-(phenylmethoxy)-6-heptene-1,2,4-triol 
• 67-64-1 acetone 
• 120520-95-8 (2S,3S,4R)-3-(phenylmethoxy)-6-heptene-1,2,4-triol 
• 104322-67-0 (R)-2-Benzyloxy-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol 
• 100-39-0 benzyl bromide 
• 38270-72-3 dimethyl 2,3-O-benzylidene-L-tartrate 
• 100906-42-1 2-O-benzyl-3,4-O-isopropylidene-L-threose 
• 762-72-1 allyl-trimethyl-silane 
• 1802-55-7 diallylzinc 
• 104322-68-1 (2S)-benzyloxy-[(4S)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetaldehyde 
• 89755-56-6 (3aR,6S,6aR)-5-Allyl-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 120417-96-1 <3aR(3aα,5β,6α,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole 
• 63593-02-2 3-O-benzyl-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose 
• 24850-33-7 allyltributylstanane 

Downstream Products

• 1268616-18-7 (2S,3R,4R)-3-(benzyloxy)-4-(methoxymethoxy)hept-6-ene-1,2-diol 
• 1268616-26-7 C₂₂H₃₈O₅Si 
• 1268616-19-8 (2S,3R,4R)-3-(benzyloxy)-1-(tert-butyldimethylsilyloxy)-4-(methoxymethoxy)-2-(p-toluenesulfonyloxy)-hept-6-ene 
• 1268616-25-6 C₁₉H₂₈O₅ 
• 111462-29-4 Benzoic acid (2S,3R,4S)-6-acetoxy-2-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-4-yl ester 
• 111462-28-3 Benzoic acid (S)-1-[(R)-benzyloxy-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-but-3-enyl ester 
• 1340476-24-5 (2S,3R,4R)-3-(benzyloxy)-2-hydroxy-4-(methoxymethoxy)hept-6-enyl 4-methylbenzenesulfonate 
• 1340476-27-8 (3R,4R,5R)-N-benzyl-4-(benzyloxy)-5-((E)-tetradec-2-en-1-yl)tetrahydrofuran-3-amine 
• 1340476-26-7 (3R,4R,5R)-5-allyl-N-benzyl-4-(benzyloxy)tetrahydrofuran-3-amine 
• 1340476-25-6 (3S,4S,5R)-5-allyl-4-(benzyloxy)tetrahydrofuran-3-yl 4-methylbenzenesulfonate 
• 111462-29-4 Benzoic acid (2S,3S,4S)-6-acetoxy-2-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-4-yl ester 
• 111555-40-9 (4S)-4-<(1S,2R)-1-(phenylmethoxy)-2-(benzoyloxy)-4-penten-1-yl>-2,2-dimethyl-1,3-dioxole 
• 111462-28-3 Benzoic acid (S)-1-[(S)-benzyloxy-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-but-3-enyl ester 
• 111462-29-4 Benzoic acid (2S,3R,4R)-6-acetoxy-2-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

Stereoselective total synthesis of (+)-synargentolide A

The stereoselective synthesis of synargentolide A, a polyhydroxy δ-lactone, has been accomplished from tartaric acid. The key steps in the synthesis involve Keck and Brown allylations and ring closing metathesis.

New Chirons from D-Glucose. Regio- and Diastereoselective C-C Bond Forming Reactions Exploiting Novel Aldotetrafuranose Acetates as Chiral Synthetic Equivalents of Tartaric Aldehydes

Two differentially protected tetrafuranose acetates 5 and 6 have been prepared from diacetone D-glucose in parallel short routes.They clearly act as chiral synthetic equivalents of D- and meso-tartaric aldehydes when exploited in Lewis acid promoted react

STEREOSELECTIVE ALLYLATION FOR PREPARATION OF L-HEXOSE DERIVATIVES

The reaction of allyltrimethylsilane with α,β-dialkoxyaldehydes is catalyzed by magnesium bromide, and provides for a highly stereoselective allylation which is predicted by α-chelation of the Lewis acid.The observed stereocontrol is opposite to that gene