120517-32-0

Basic information

• Product Name: 1H-Indole, 1-methyl-2-(phenylthio)-
• CAS NO: 120517-32-0
• Molecular Formula: C15H13NS
• Molecular Weight: 239.341
• Mol File: 120517-32-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1H-Indole, 1-methyl-2-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indole, 1-methyl-2-(phenylthio)-(120517-32-0)
• EPA Substance Registry System: 1H-Indole, 1-methyl-2-(phenylthio)-(120517-32-0)

Safety Data

• Hazardous Substances Data: 120517-32-0(Hazardous Substances Data)

Upstream product

• 603-76-9 1-methylindole 
• 596819-10-2 1-methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole 
• 882-33-7 diphenyldisulfane 
• 98-09-9 benzenesulfonyl chloride 
• 873-55-2 sodium benzenesulfonate 
• 61-70-1 N-methyl-2-indolinone 
• 591-50-4 iodobenzene 
• 13637-38-2 1-methyl-2-indolinethione 
• 108-98-5 thiophenol 
• 14204-24-1 N-(phenylthio)succinimide 
• 63955-67-9 1-methyl-3-(phenylthio)-1H-indole 
• 55402-02-3 N-<13C>methylindole 
• 63955-64-6 1-methyl-2,3-bis(phenylthio)-1H-indole 
• 54491-43-9 3-phenylthioindole 

Relevant articles and documents

Benzoic Acid-Promoted C2-H Borylation of Indoles with Pinacolborane

A benzoic acid-promoted C2-H borylation of indoles with pinacolborane to afford C2-borylated indoles is developed. Preliminary mechanistic studies indicate BH3-related borane species formed via the decomposition of pinacolborane to be the probable catalyst. This transformation provides a prompt route toward the synthesis of diverse C2-functionalized indoles.

Copper-catalyzed synthesis of 2-sulfenylindoles from indoline-2-thiones and aryl iodides

A novel and efficient method for synthesis of 2-sulfenylindole via copper-catalyzed coupling reaction of indoline-2-thiones with aryl iodides has been developed. A series of N-substituted and N-free 2-sulfenylindole were obtained in high yields. Furthermo

Nonreductive Desulfenylation of 3-Indolyl Sulfides. Improved Syntheses of 2-Substituted Indoles and 2-Indolyl Sulfides

Desulfenylation of 3-indolyl sulfides to the corresponding 3-unsubstituted indoles is usually carried out under reductive conditions, thus accommodating only substituents which are resistant to reduction.We have developed a nonreductive procedure for removal of a sulfide at the 3-position of indoles, using trifluoroacetic acid in the presence of a thiol as trapping agent, which is compatible with a large array of functionalities on the indole ring.In addition, the desulfenylation occurs selectively at the 3-position of the indole, and sulfide groups at other positions of the molecule remain untouched.Thus, indole 2,3-bis-sulfides are selectively desulfenylated at the 3-position, affording 3-unsubstituted 2-indolyl sulfides.This methodology broadens the use of sulfide as a protecting group for the 3-position of indoles.