120546-89-6

Basic information

• Product Name: N-_α-Benzoylhistidine methyl ester
• Synonyms: N-_α-Benzoylhistidine methyl ester
• CAS NO: 120546-89-6
• Molecular Weight: 273.291
• Mol File: 120546-89-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-_α-Benzoylhistidine methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-_α-Benzoylhistidine methyl ester(120546-89-6)
• EPA Substance Registry System: N-_α-Benzoylhistidine methyl ester(120546-89-6)

Safety Data

• Hazardous Substances Data: 120546-89-6(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 858221-92-8 2-benzoylamino-3-(2,5-dithioxo-imidazolidin-4-yl)-acrylic acid methyl ester 

Downstream Products

• 120546-81-8 2-({3-[4-(2-Benzoylamino-2-methylcarbamoyl-ethyl)-imidazol-1-ylmethyl]-2-hydroxy-tetrahydro-furan-2-carbonyl}-amino)-3,4-dihydroxy-4-methyl-tetrahydro-furan-2-carboxylic acid amide 
• 120546-83-0 (dl)-N_α-Benzoyl-N-1-(3-oxobut-1-yl)histidine methylamide 
• 125039-07-8 (S)-2-Benzoylamino-3-[1-(4-nitro-benzenesulfonyl)-1H-imidazol-4-yl]-propionic acid methyl ester 
• 14056-33-8 N^α-benzoyl-DL-histidine 
• 65096-22-2 (-)-N(?)-methyl-N(α)-benzoyl-L-histidinol 
• 35166-51-9 methyl ester of N^α-benzoyl-N^?-methyl-L-histidine 
• 152774-38-4 Methyl N^α-benzoyl-2-<2'-(phenylseleno)ethyl>-N^τ-tritylhistidinate 
• 152774-44-2 Methyl N^α-benzoyl-N^τ-trityl-2-vinylhistidinate 
• 152774-33-9 N-Benzoyl-2-<(1'-trityl-4'-imidazoyl)methyl>homoserine lactone 
• 120546-75-0 (dl)-N_α-Benzoylhistidine methylamide 

Relevant articles and documents

Histidine and deuterium labelled histidine by asymmetric catalytic reduction with gaseous H2 or D2; the role of strong non-coordinating acids

An efficient and convenient route for the preparation of natural and unnatural histidine by asymmetric hydrogenation with rhodium-phosphine complexes is described. The reductions were performed in the presence of HBF4 to generate an essential imidazolyl cation. Stereoselective incorporation of D2 in the α,β-positions was obtained by catalytic deuteration in the presence of MeOD.