120547-05-9

Upstream product

• 1631-82-9 chloro(methyl)phenylsilane 
• 144-79-6 chloromethyldiphenylsilane 
• 100-58-3 phenylmagnesium bromide 
• 100-59-4 phenylmagnesium chloride 
• 1172-76-5 1,2-dimethyl-1,1,2,2-tetraphenyldisilane 
• 134134-79-5 1-Chloro-1,2-dimethyl-1,2,2-triphenyl-disilane 

Relevant academic research and scientific papers

Reactions of methylchlorodisilanes with Grignard reagents

Reactions of Cl2MeSiSiMeCl2 with RMgCl make it possible to obtain and isolate pure disilanes containing a smaller number of functional groups, namely, RMeClSiSiMeCl2 (R = Ph), RMeClSiSiMeRCl (R = Pri, Ph), and R2MeSiSiMeRCl (R = Bui).The reaction of Cl2MeSiSiMeCl2 with BunMgCl is the least selective.The chlorides obtained were reduced with LiAlH4 into the corresponding hydrides.

Synthesis and Photochemical Deoligomerizations of a Series of Isomeric Disilyliron Complexes: (η5-C5H5)Fe(CO)2Si2Ph3-nMe2+n

A series of six disilyl complexes of the general type (η5-C5H5)Fe(CO)2Si2Ph3-n)Me2+n, representing three isomeric pairs, have been synthesized and characterized.Photolysis of each complex leads to the formation of a series