134134-79-5Relevant academic research and scientific papers
Reactions of methylchlorodisilanes with Grignard reagents
Semenov, V. V.,Ladilina, E. Yu.,Chesnokova, T. A.,Elistratova, N. K.,Kurskii, Yu. A.,Makarenko, N. P.
, p. 927 - 930 (1995)
Reactions of Cl2MeSiSiMeCl2 with RMgCl make it possible to obtain and isolate pure disilanes containing a smaller number of functional groups, namely, RMeClSiSiMeCl2 (R = Ph), RMeClSiSiMeRCl (R = Pri, Ph), and R2MeSiSiMeRCl (R = Bui).The reaction of Cl2MeSiSiMeCl2 with BunMgCl is the least selective.The chlorides obtained were reduced with LiAlH4 into the corresponding hydrides.
