120622-90-4

Basic information

• Product Name: N,N-bis(methanesulfonyl)benzamide
• Synonyms: N,N-bis(methanesulfonyl)benzamide
• CAS NO: 120622-90-4
• Molecular Weight: 277.322
• Mol File: 120622-90-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N,N-bis(methanesulfonyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis(methanesulfonyl)benzamide(120622-90-4)
• EPA Substance Registry System: N,N-bis(methanesulfonyl)benzamide(120622-90-4)

Safety Data

• Hazardous Substances Data: 120622-90-4(Hazardous Substances Data)

Upstream product

• 5347-82-0 dimesylamine 
• 98-88-4 benzoyl chloride 
• 87293-07-0 trimethyl(dimesylamino)stannane 
• 87293-07-0 trimethyl(dimesylamino)stannane 
• 30488-11-0 silver(I) dimesylamide 
• 30488-04-1 trimethylsilyldimesylamine 

Downstream Products

• 119-61-9 benzophenone 
• 134-85-0 4-chlorobenzophenone 
• 345-83-5 4-fluorobenzophenone 
• 134-84-9 4-Methylbenzophenone 
• 22679-54-5 4-tert-butylbenzophenone 
• 611-94-9 4-Methoxybenzophenone 
• 728-86-9 phenyl[4-(trifluoromethyl)phenyl]methanone 
• 53689-84-2 4-acetylbenzophenone 
• 644-13-3 C₆H₅COC₁₀H₇ 
• 2128-93-0 biphenyl-4-yl-phenyl-methanone 

Relevant articles and documents

Palladium-Catalyzed Carbonylative Coupling Reactions of N,N-Bis(methanesulfonyl)amides through C–N Bond Cleavage

Palladium-catalyzed carbonylative coupling reactions of various N,N-bis(methanesulfonyl)amides with arylboronic acids through C–N bond cleavage were carried out. The reactions proceeded under mild conditions in a short period of time without any additives to afford a wide range of unsymmetrical aryl ketones in excellent yields. This is the first example of a carbonylative coupling reaction using N,N-bis(methanesulfonyl)amide as a coupling substrate.

Polysulfonylamines, XII. N-Acyl Dimesylamines (Carboxylic Acid N,N-Dimesylamides)

N-Acyl dimesylamines RC(O)N(SO2CH3)2 (3) have been prepared by reacting solid KN(SO2CH3)2 with neat liquid RC(O)Cl at 70-90 deg C or solutions of AgN(SO2CH3)2 in methyl cyanide with RC(O)Cl at room temperature .Addition of chlorine or bromine to 3 (R = CH2=CH) affords the corresponding compounds 3 with R = CH2Cl-CHCl and CH2Br-CHBr, respectively.By hydrolysis of 3 (R = CCl3), CCl3C(O)NHSO2CH3 (5) is obtained.The new compounds 3 and 5 are characterized by spectroscopic (NMR, MS) and analytical methods. - Keywords: N-Acyl Dimesylamines, Potassium and Silver Dimesylaminides, Acyl Chlorides