120677-10-3Relevant academic research and scientific papers
PROTECTION DES ACIDES PAR LES GROUPEMENTS ABz. UTILISATION EN SYNTHESE PEPTIDIQUE
Loubinoux, Bernard,Gerardin, Philippe
, p. 239 - 248 (2007/10/02)
The novel azidomethoxybenzyl esters (ABz esters) of various acids are easily obtained and are cleanly cleaved in very mild reductive conditions.Such esters serve to protect the carboxyl group in peptide synthesis without any racemisation.
PROTECTION DES PHENOLS PAR LE GROUPEMENT AZIDOMETHYLENE APPLICATION A LA SYNTHESE DE PHENOLS INSTABLES
Loubinoux, Bernard,Tabbache, Samir,Gerardin, Philippe,Miazimbakana, Joseph
, p. 6055 - 6064 (2007/10/02)
Phenols are protected by the azidomethylene group in basic, nucleophilic, oxidative, weakly reductive and weakly acidic media.This group is obtained by the reaction of sodium azide with aryloxymethyl chlorides.Its utility lies in the ease with which it can be removed under very mild conditions which allows the synthesis of very unstable phenolic compounds.
