120878-74-2

Upstream product

• 119-61-9 benzophenone 
• 95-15-8 Benzo[b]thiophene 
• 36748-89-7 2-iodobenzothiophene 
• 464-72-2 tetraphenylethane-1,2-diol 

Downstream Products

• 936734-95-1 2-(2'-fluorophenyl)benzo[b]thiophene 
• 63676-27-7 2-(4-chlorophenyl)-benzo[b]thiophene 
• 1207-95-0 2-phenylbenzo[b]thiophene 
• 936734-94-0 2-(2-chlorophenyl)-benzo[b]thiophene 
• 17164-77-1 2-(naphthalen-2-yl)benzo[b]thiophene 
• 25664-47-5 2-(4-methylphenyl)benzo[b]thiophene 
• 55084-51-0 2-(2-methylphenyl)-1-benzothiophene 
• 78176-92-8 2-(naphthalen-1-yl)benzo[b]thiophene 
• 936734-96-2 2-(4-fluoro-phenyl)-benzo[b]thiophene 

Relevant academic research and scientific papers

Sodium-Ketyl Radical Anions by Reverse Pinacol Reaction and Their Coupling with Iodoarenes

Transition-metal-free C-C bond formation between aryl iodides and pinacols is presented. Pinacols are readily transformed by deprotonation with NaH to their Na-pinacolates. C-C-bond homolysis at room temperature generates in situ the corresponding Na-ketyl radical anions which react with various aryl iodides in a homolytic aromatic substitution reaction to form tertiary Na-alcoholates. Protonation eventually provides tertiary alcohols in an unprecedented route.

Organocatalytic deprotonative functionalization of C(sp2)-H and C(sp3)-H bonds using in situ generated onium amide bases

Onium amides, generated in situ from the combination of aminosilanes and onium fluorides (R4PF, R4NF), are employed for the first time as bases for catalytic deprotonative functionalization of C(sp 2)-H and activated C(sp

Selective palladium-catalysed ipso arylation of α,α- disubstituted benzo[b]thien-2-ylmethanols with aryl bromides using PCy 3 as ligand

α,α-Diphenylbenzo[b]thien-2-ylmethanol was treated with a series of aryl bromides in the presence of palladium(II) acetate and tricyclohexylphosphane to give the appropriate 2-aryl-benzo[b]thiophenes in good to excellent yield with concomitant formation o