120927-64-2Relevant academic research and scientific papers
Intramolecular Radical Cyclizations of 2-Deoxy-2-iodohexopyranoside Derivatives: Routes to Densely Functionalized Carbocycles.
Vite, Gregory D.,Alonso, Ricardo,Fraser-Reid, Bert
, p. 2268 - 2271 (1989)
2-Deoxy-2-iodohexopyranosides containing appropriate traps at C6 or C7 undergo radical cyclization to give oxabicyclo or systems whose glicosidic bonds are readily cleaved to afford densely functionalized cyclopentanes or cyclohexanes.
Radical Cyclization Routes to Bridged Pyranosides as Precursors of Densely Functionalized Cycloalkanes
Alonso, R. A.,Vite, G. D.,McDevitt, R. E.,Fraser-Reid, B.
, p. 573 - 584 (2007/10/02)
Glycals derived from hexapyranoses permit the incorporation of iodine at C-2 as well as elaboration of an olefinic residue via the C-5-hydroxymethyl group.Radical cyclization of these functionalities leads to bicyclic systems whose bridge sizes depend on
