120927-71-1

Upstream product

• 120927-67-5 [(1S,3S,4S,6S,7S,8R)-7,8-Bis-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2-oxa-bicyclo[2.2.2]oct-5-yl]-acetic acid ethyl ester 
• 120964-43-4 [(1R,3S,4S,5R,6S,7S,8R)-7,8-Bis-benzyloxy-6-hydroxy-3-(4-methoxy-benzyloxy)-2-oxa-bicyclo[2.2.2]oct-5-yl]-acetic acid ethyl ester 
• 98-88-4 benzoyl chloride 
• 109-80-8 1.3-propanedithiol 
• 120927-70-0 Benzoic acid (1R,3S,4S,5R,6S,7S,8R)-7,8-bis-benzyloxy-5-ethoxycarbonylmethyl-3-(4-methoxy-benzyloxy)-2-oxa-bicyclo[2.2.2]oct-6-yl ester 

Downstream Products

• 120927-72-2 Ethyl 6-(Benzoyloxy)-3,4-bis(benzyloxy)-5-hydroxy-2-<2-(1,3-dithianyl)>cyclohex-1-ylacetate 

Relevant academic research and scientific papers

Radical Cyclization Routes to Bridged Pyranosides as Precursors of Densely Functionalized Cycloalkanes

Glycals derived from hexapyranoses permit the incorporation of iodine at C-2 as well as elaboration of an olefinic residue via the C-5-hydroxymethyl group.Radical cyclization of these functionalities leads to bicyclic systems whose bridge sizes depend on

Intramolecular Radical Cyclizations of 2-Deoxy-2-iodohexopyranoside Derivatives: Routes to Densely Functionalized Carbocycles.

2-Deoxy-2-iodohexopyranosides containing appropriate traps at C6 or C7 undergo radical cyclization to give oxabicyclo or systems whose glicosidic bonds are readily cleaved to afford densely functionalized cyclopentanes or cyclohexanes.