1209413-30-8Relevant academic research and scientific papers
Et3B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita-Baylis-Hillman alcohols
Abidi, Ahlem,Oueslati, Yosra,Rezgui, Farhat
supporting information, p. 2402 - 2409 (2016/12/09)
A practical and efficient palladium-catalyzed direct allylation of β-dicarbonyl compounds with both cyclic and acyclic Morita-Baylis-Hillman (MBH) alcohols, using Et3B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been obtained in good yields and with high selectivity.
The first DMAP-mediated palladium-free Tsuji-Trost-type reaction of cyclic and acyclic Baylis-Hillman alcohols with active methylene compounds
Mhasni, Olfa,Rezgui, Farhat
experimental part, p. 586 - 587 (2010/04/02)
Direct allylic substitution of cyclic Baylis-Hillman alcohols with active methylene compounds under modified Taber's conditions (DMAP, toluene, reflux, 4 ? molecular sieves), with no Pd catalysts/activating agents, as is usually required for the process, affords the C-allylation products in moderate to good yields.
