12099-10-4

Basic information

• Product Name: N,N,N-triethylethanaminium tetraphenylborate(1-)
• Synonyms: N,N,N-Triethylethanaminium tetraphenylborate(1-)
• CAS NO: 12099-10-4
• Molecular Formula: C₈H₂₀N*C₂₄H₂₀B
• Molecular Weight: 449.4777
• Mol File: 12099-10-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N,N-triethylethanaminium tetraphenylborate(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: N,N,N-triethylethanaminium tetraphenylborate(1-)(12099-10-4)
• EPA Substance Registry System: N,N,N-triethylethanaminium tetraphenylborate(1-)(12099-10-4)

Safety Data

• Hazardous Substances Data: 12099-10-4(Hazardous Substances Data)

Upstream product

• 67292-38-0 tetraethylammonium hexacarbonyltantalate 
• 143-66-8 sodium tetraphenyl borate 
• 62432-82-0 Aethoxydimorpholinosulfonium-Tetraphenylborat 
• 121-44-8 triethylamine 

Relevant articles and documents

A facile atmospheric pressure synthesis of the hexacarbonylmetalate ions, M(CO)6-, of niobium and tantalum

Treatment of the pentachlorides of niobium and tantalum with 6 equiv of alkali-metal naphthalenide or 1-methylnaphthalenide in DME at -60 to -80°C provides thermally unstable red-brown intermediates that may be M(C10H8)2- or M(1-MeC10H7)2- (M = Nb, Ta). These species readily react with CO at atmospheric pressure at -60°C to provide 30-54% yields of the corresponding M(CO)6-, isolated as Et4N+, n-Bu4N+, and Na(diglyme)2+ salts. This two-step reductive carbonylation procedure is the first reported atmospheric pressure synthesis of the hexacarbonylmetalate(1-) ions of niobium and tantalum. The synthesis and properties of unsolvated NaTa(CO)6 are also described.