67292-38-0

Upstream product

• 111532-96-8 cis-{(C₂H₅)4N}{Ta(CO)4P{CH₂CH₂P(C₆H₅)2}3} 

Downstream Products

• 111532-96-8 cis-{(C₂H₅)4N}{Ta(CO)4P{CH₂CH₂P(C₆H₅)2}3} 
• 34134-63-9 cis-{(C₂H₅)4N}{Ta(CO)4(C₆H₅)2PCH₂CH₂P(C₆H₅)2} 
• 111834-55-0 cis-{(C₂H₅)4N}{Ta(CO)4{(C₆H₅)2PCH₂CH₂P(C₆H₅)2}2} 
• 111532-99-1 Ta(H)(CO)3{(C₆H₅)2PCH₂CH₂P(C₆H₅)CH₂}2} 
• 247122-17-4 Ta(CN(CH₃)2C₆H₃)7⁽¹⁺⁾*BF₄^(1-)=[Ta(CN(CH₃)2C₆H₃)7]BF₄ 
• 247122-19-6 Ta(CNC₆H₃(CH₃)2)6I 
• 15602-40-1 Na⁽¹⁺⁾*Ta(CO)6^(1-) = Na(Ta(CO)6) 
• 12099-10-4 tetraethylammonium tetraphenylborate 

Relevant academic research and scientific papers

The seven-coordinate hydrido-tantalum complexes 6-n(oligophos)>: preparation and dynamics

The hydrido complexes cis-2> (P2 = Ph2PCH2CH2PPh2), HTa(CO)3Pm (Pm = P3: PhP(CH2CH2PPh2)2, P4: 2, PP3: P(CH2CH2PPh2)3) have been obtained from the photo-chemically produced complexes m> by ion-exchange chromatography on silica gel.The anionic and neutral complexes have been characterized by IR and 31P and 1H NMR spectroscopy.The temperature-dependent 1H(hydride)-31P NMR coupling patterns are interpreted in terms os a hydride-capped octahedral structure with restricted migration of the H(-) ligand between the octahedral faces.