1210-12-4

Basic information

• Product Name: 9-Anthrracenecarbonitrile
• Synonyms: LABOTEST-BB LT00159449;AKOS B004035;9-ANTHRACENECARBONITRILE;9-CYANOANTHRACENE;9-Anthronitrile;anthracene-9-carbonitrile;9-Anthracenecarbonitrille, 98%;9-Anthracen-Carboxylic Acid
• CAS NO: 1210-12-4
• Molecular Formula: C₁₅H₉N
• Molecular Weight: 203.24
• EINECS: 214-909-7
• Product Categories: Aromatic Nitriles;Anthracenes
• Mol File: 1210-12-4.mol
• Article Data: 81

Chemical Properties

• Melting Point: 173-177 °C(lit.)
• Boiling Point: 413.794 °C at 760 mmHg
• Flash Point: 205.393 °C
• Appearance: solid
• Density: 1.208 g/cm₃
• Vapor Pressure: 4.67E-07mmHg at 25°C
• Refractive Index: 1.719
• Water Solubility: Insoluble in water.
• BRN: 1911437
• CAS DataBase Reference: 9-Anthrracenecarbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Anthrracenecarbonitrile(1210-12-4)
• EPA Substance Registry System: 9-Anthrracenecarbonitrile(1210-12-4)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36
• RIDADR: 3276
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 6.1
• PackingGroup: III
• Hazardous Substances Data: 1210-12-4(Hazardous Substances Data)

Usage

Chemical Properties

solid

Uses

Different sources of media describe the Uses of 1210-12-4 differently. You can refer to the following data:
1. Anthracene-9-carbonitrile was used to study the mechanism of charge separation within phenothiazine (PTZH) or phenoxazine (PXZH), and 9-cyanoanthracene(electron acceptor). Also it has been used to study the fluorescence excitation spectra of this compound .
2. 9-Anthracenecarbonitrile was used to study the mechanism of charge separation within phenothiazine (PTZH) or phenoxazine (PXZH), and 9-cyanoanthracene(electron acceptor).

General Description

The fluorescence excitation spectra of 9-anthracenecarbonitrile has been studied.

Purification Methods

Crystallise the nitrile from EtOH or toluene, and sublime it in a vacuum in the dark under N2 [Ebied et al. J Chem Soc, Faraday Trans 1 76 2170 1980, Kikuchi et al. J Phys Chem 91 574 1987]. [Beilstein 9 I 304.]

InChI:InChI=1/C15H9N/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H

Upstream product

• 506-68-3 bromocyane 
• 120-12-7 anthracene 
• 602-60-8 9-nitroanthracene 
• 143-33-9 sodium cyanide 
• 98398-56-2 5-(9-anthryl)-2H-tetrazole 
• 1217-45-4 9,10-Dicyanoanthracene 
• 75-05-8 acetonitrile 
• 642-31-9 9-anthracene aldehyde 
• 2476-68-8 9-(aminomethyl)anthracene 
• 931-97-5 1-hydroxy-1-cyclohexanecarbonitrile 
• 723-62-6 anthracen-9-carboxylic acid 
• 1564-64-3 9-Bromoanthracene 
• 68-12-2 N,N-dimethyl-formamide 
• 523-27-3 9,10-Dibromoanthracene 

Downstream Products

• 623-26-7 terephthalonitrile radical anion 
• 100-25-4 1,4-dinitroanthracene radical anion 
• 623-26-7 terephthalonitrile 
• 642-31-9 9-anthracene aldehyde 
• 602-60-8 9-nitroanthracene 
• 1213-82-7 9-chloro-10-cyano-anthracene 
• 2476-68-8 9-(aminomethyl)anthracene 
• 93324-64-2 9-cyano-9,10-dihydro-9,10-ethanoanthracene 
• 97015-27-5 10-benzyl-9,10-dihydro-anthracene-9-carbonitrile 
• 120-12-7 anthracene 
• 779-02-2 9-methylanthracene 
• 33998-38-8 9-cyanoanthracene photodimer 

Relevant articles and documents

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Gallium-containing polymer brush film as efficient supported Lewis acid catalyst in a glass microreactor

Polystyrene sulfonate polymer brushes, grown on the interior of the microchannels in a microreactor, have been used for the anchoring of gallium as a Lewis acid catalyst. Initially, gallium-containing polymer brushes were grown on a flat silicon oxide surface and were characterized by FTIR, ellipsometry, and X-ray photoelectron spectroscopy (XPS). XPS revealed the presence of one gallium per 2-3 styrene sulfonate groups of the polymer brushes. The catalytic activity of the Lewis acid-functionalized brushes in a microreactor was demonstrated for the dehydration of oximes, using cinnamaldehyde oxime as a model substrate, and for the formation of oxazoles by ring closure of ortho-hydroxy oximes. The catalytic activity of the microreactor could be maintained by periodic reactivation by treatment with GaCl3.

Preparation of 14C-labeled multiwalled carbon nanotubes for biodistribution investigations

(Figure Presented) A new method allowing the 14C-labeling of carboxylic acid functions of carbon nanotubes is described. The key step of the labeling process is a decarbonylation reaction that has been developed and optimized with the help of a screening method. The optimized process has been successfully applied to multiwalled carbon nanotubes (MWNTs), and the corresponding 14C-labeled nanotubes were used to investigate their in vivo behavior. Preliminary results obtained after i.v. contamination of rats revealed liver as the main target organ. Radiolabeling of NTs with a long-life radioactive nucleus like 14C, coupled to a highly sensitive autoradiographic method, that provides a unique detection threshold, will make it possible to determine for a long time period whether or not NTs remain in any organs after animal exposure.

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Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity

A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1′R)-1,1′-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied.

CuO-catalyzed conversion of arylacetic acids into aromatic nitriles with K4Fe(CN)6 as the nitrogen source

Readily available CuO was demonstrated to be effective as the catalyst for the conversion of arylacetic acids to aromatic nitriles with non-toxic and inexpensive K4Fe(CN)6 as the nitrogen source via the complete cleavage of the C[tbnd]N triple bond. The present method allowed a series of arylacetic acids including phenylacetic acids, naphthaleneacetic acids, 2-thiopheneacetic acid and 2-furanacetic acid to be converted into the targeted products in low to high yields.

Copper-Catalyzed One-Pot Synthesis of Quinazolinones from 2-Nitrobenzaldehydes with Aldehydes: Application toward the Synthesis of Natural Products

A novel, efficient, and atom-economical approach for the construction of quinazolinones from 2-nitrobenzaldehydes has been unveiled via copper-catalyzed nitrile formation, hydrolysis, and reduction in one pot for the first time. In this reaction, urea is used as a source of nitrogen for nitrile formation, hydrazine hydrate is used for both the reduction of the nitro group and the hydrolysis of nitrile, and atmospheric oxygen is used as the sole oxidant. The method portrays a wide substrate scope with good functional group tolerances. Moreover, this method was applied for the synthesis of schizocommunin, tryptanthrin, phaitanthrin-A, phaitanthrin-B, and 8H-quinazolino[4,3-b]quinazolin-8-one.