1210801-41-4

Upstream product

• 1493-27-2 ortho-nitrofluorobenzene 
• 108-59-8 malonic acid dimethyl ester 
• 26465-37-2 dimethyl 2-(2-nitrophenyl)malonate 
• 86162-61-0 C₁₁H₁₃NO₄ 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1210801-56-1 C₂₂H₂₃NO₇S 
• 1210801-59-4 C₂₂H₂₃NO₈S 
• 1210801-57-2 C₂₇H₂₅NO₇S 
• 1257322-07-8 dimethyl-1-(4-methylphenylsulfonyl)-3-vinyl-2,3-dihydroquinoline-4,4(1H)-dicarboxylate 
• 1393094-72-8 C₂₂H₂₃NO₇S 
• 1393094-70-6 C₂₂H₂₃NO₇S 

Relevant academic research and scientific papers

Regio- and enantioselective synthesis of functionalized tetrahydroquinolines by palladium-catalyzed cyclization of 2- amidophenylmalonates with allylic bisacetates

A palladium-catalyzed cyclization of 2-amidophenylmalonates with allylic bisacetates is described. Tetrahydroquinolines having a vinyl group at the 3- or 2-position were produced, in which the regioselectivity of the resulting products was altered depending on the substituent on the amino group. The product was transformed to the azabicyclo[3.3.1]nonene via the ring-closing metathesis. Enantioselective reactions also successfully proceeded in the presence of (S)-BINAP to give the optically active tetrahydroquinoline with high enantioselectivity.

Diphosphine-catalyzed mixed double-michael reaction: A unified synthesis of lndolines, Dihydropyrrolopyridines, Benzimidazolines, Tetrahydroquinolines, Tetrahydroisoquinolines, Dihydrobenzo-1,4-oxazines, and Dihydrobenzo-3,1- oxazines

(Figure Presented) Seven different types of benzannulated N-heterocycles-indolines, dihydropyrrolopyridlnes, benzimidazolines, dihydrobenzo-3,1-oxazines, benzomorpholines, tetrahydroquinolines, and tetrahydroisoquinolines-can be obtained from simple dinuc