121086-93-9Relevant academic research and scientific papers
FLUORIDE ION INDUCED REACTION OF PHENYLTHIOMETHYLTRIMETHYLSILANE (1) WITH ALDEHYDES AND KETONES: A SIMPLE PROCEDURE FOR THE FORMATION OF β-HYDROXYPHENYLSULPHIDES
Kitteringham, John,Mitchell, Michael B.
, p. 3319 - 3322 (1988)
The tetra n-butylammonium fluoride (TBAF) initiated reaction of phenylthiomethyltrimethylsilane (1) with aldehydes and ketones is reported. β-Hydroxy-phenylsulphides are formed in good yields even with ketones that contain enolizable protons.In contrast,
NOVEL ARYLTHIOMETHYLATION OF CARBONYL COMPOUNDS USING ARYLTHIOMETHYLTRIMETHYLSILANES CATALYZED BY FLUORIDE IONS. NEW ROUTE TO β-HYDROXYARYLSULFIDES
Hosomi, Akira,Ogata, Koichiro,Hoashi, Koichiro,Kohra, Shinya,Tominaga, Yoshinori
, p. 3736 - 3738 (2007/10/02)
Arylthiomethyltrimethylsilanes are good and mild nucleophilic reagents for introducing arylthiomethyl groups into carbonyl compounds promoted by tetra-n-butylammonium fluoride to give the corresponding β-hydroxyarylsulfides in fairly good yields.
