121155-51-9

Basic information

• Product Name: (3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol
• Synonyms: (3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol
• CAS NO: 121155-51-9
• Molecular Weight: 168.279
• Mol File: 121155-51-9.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: (3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol(121155-51-9)
• EPA Substance Registry System: (3S,4R)-4-cyclohexyl-3-methyl-1-buten-4-ol(121155-51-9)

Safety Data

• Hazardous Substances Data: 121155-51-9(Hazardous Substances Data)

Upstream product

• 4784-77-4 (E)-1-Bromo-2-butene 
• 2043-61-0 cyclohexanecarbaldehyde 
• 35998-93-7 tri-n-butylcrotyltin 
• 1280227-89-5 (1R,2S,E)-1-cyclohexyl-2-methyl-4-(tributylstannyl)but-3-en-1-ol 
• 4784-77-4 (E/Z)-crotyl bromide 
• 1106964-40-2 1-methylprop-2-ene-1-sulfonyl chloride 
• 66534-32-5 α,α-diisopropyl-β-methylhomoallylic alcohol 
• 693-03-8 n-butyl magnesium bromide 
• 100-52-7 benzaldehyde 
• 73537-46-9 (Z)-2-Butenylchlorodimethylsilane 
• 29310-15-4 (E/Z)-Crotyldimethylchlorosilane 
• 4894-61-5 trans-but-2-enyl chloride 
• 66534-82-5 3-tert-butyl-2,2,4-trimethyl-hex-5-en-3-ol 
• 591-97-9 1-chloro-2-butene 

Downstream Products

• 93965-54-9 (1RS,2RS)-N-phenylmethyl-1-cyclohexyl-2-methyl-3-buten-1-amine 
• 93965-54-9 (1RS,2SR)-N-phenylmethyl-1-cyclohexyl-2-methyl-3-buten-1-amine 
• 122200-72-0 trans-1-cyclohexyl-2-methyl-1,4-butanediol 
• 105401-07-8 (1R,2S)-1-cyclohexyl-2-methyl-1,3-propanediol 
• 129170-75-8 (1S,2R)-1-cyclohexyl-2-methyl-1,3-propane diol 
• 129065-04-9 (1S,2S)-1-cyclohexyl-2-methylbutan-1-ol 

Relevant articles and documents

Photocatalytic Generation of π-Allyltitanium Complexes from Butadiene via a Radical Strategy

The direct conversion of industrial feedstock chemicals into highly valuable fine chemical intermediates is of great appeal to the synthetic community as well as industrial applications. This study reports a conceptually new radical strategy for the photocatalytic generation of π-allyltitanium complexes from butadiene. This novel and environmentally benign strategy enables the direct three-component allylation of carbonyls with 1,3-butadiene and α-bromocarboxylates, providing rapid access to valuable homoallylic alcohols with exceptional regio- and diastereoselectivity control.

Titanocene(III)-promoted Barbier-type crotylation of carbonyl compounds

A mild, highly regio-and stereoselective method for the crotylation of aldehydes and ketones mediated/catalyzed by titanocene(III) is described. Optimized conditions permit the selective generation of γ-adducts in high yields together with high stereoselectivity, with a predominance of anti stereoisomers.

Enantioconvergent hydroboration of a racemic allene: Enantioselective synthesis of (E)-δ-stannyl- anti -homoallylic alcohols via aldehyde crotylboration

The enantioconvergent hydroboration of racemic allenylstannane (±)-1 with (dIpc)2BH converts both enantiomers of (±)-1 into the enantioenriched crotylborane (S)-E-3. Subsequent crotylboration of aldehydes with (S)-E-3 provides (E)-st