121224-85-9Relevant academic research and scientific papers
DIASTEREOCONTROLLED NICKEL(O)- AND PALLADIUM(O) CATALYZED "METALLO-ENE-TYPE" CYCLIZATIONS/CARBONYLATIONS
Oppolzer, Wolfgang,Keller, Thomas H.,Bedoya-Zurita, Manuel,Stone, Charles
, p. 5883 - 5886 (2007/10/02)
Treatment of 1-iodo(acetoxy)-2,7-octadienes 1 and 1-iodo(acetoxy)-2-en-7-ynes 12 with Ni(COD)2/dppb (THF/MeOH) or Pd(dba)2/PPh3 (AcOH, then CH2N2) under carbon monoxide furnished chemo- and stereoselectively either bicyclic ketoesters 7 (from 1) and 15 (f
NICKEL-CATALYZED INTRAMOLECULAR ALLYLATION OF ALKENES AND ALKYNES COUPLED WITH β-ELIMINATION OR CARBONYLATION
Oppolzer, Wolfgang,Bedoya-Zurita, Manuel,Switzer, Christopher Y.
, p. 6433 - 6436 (2007/10/02)
Intramolecular allylations, combined with either β-eliminations (1 -> 2) or carbonylations (10 -> 12 + 13, 14 -> 16 and 17 -> 19 + 20) were catalyzed by Pt(PPh3)4, Ni(COD)/dppb, or Ni(CO)3PPh3, respectively.
