121239-89-2Relevant academic research and scientific papers
ANODIC OXIDATION OF DIARYLACETYLENES AND DIARYLDIACETYLENES: ELECTROSYNTHESIS OF DIAROYL-STILBENES AND ACETYLENIC α- AND γ-DIKETONES
Cariou, Michel
, p. 799 - 808 (2007/10/02)
Diarylacetylenes and diaryldiacetylenes have been electrooxidized in acetonitrile through the use of a graphite plate anode, thus overcoming a very high passivation.Diarylacetylenes led mainly to 1,2-diaroyl-1,2-diaryl-ethylenes.Anodic oxidation of conjugated diaryldiacetylenes, at the same anode, led to a mixture of acetylenic α- and γ-diketones.This represents the very first synthesis of acetylenic α-diketones Ar-CO-CO-CC-Ar.
Electro-oxidation of Diarylacetylenes and Diaryldiacetylenes
Cariou, Michel,Simonet, Jacques
, p. 445 - 446 (2007/10/02)
Diarylacetylenes led to 1,2-diaroyl-1,2-diarylethylenes and diaryldiacetylenes led to a mixture of acetylenic α- and γ-diketones, by anodic oxydation in MeCN-LiClO4 on a graphite plate electrode.
Color Change (Yellow-Orange) of 4,6,7-Tri(alkoxy-substituted aryl)-1,2,5-thiadiazolopyridines in the Solid Phase
Mataka, Shuntaro,Takahashi, Kazufumi,Tashiro, Masashi,Lin, Wei-Hua,Iwasaki, Shin-ichi,et al.
, p. 215 - 219 (2007/10/02)
Reversible color change of 4,6,7-tri(alkoxy-substituted phenyl)-1,2,5-thiadiazolopyridines 5 in the solid state was observed: on grinding, yellow crystals of 5 became an orange amorphous solid which, on heating or washing with an appropriate solven
