121411-08-3

Basic information

• Product Name: (4-Methoxy-phenyl)-[(S)-1-phenyl-2-((R)-toluene-4-sulfinyl)-ethyl]-amine
• Synonyms: (4-Methoxy-phenyl)-[(S)-1-phenyl-2-((R)-toluene-4-sulfinyl)-ethyl]-amine
• CAS NO: 121411-08-3
• Molecular Weight: 365.496
• Mol File: 121411-08-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4-Methoxy-phenyl)-[(S)-1-phenyl-2-((R)-toluene-4-sulfinyl)-ethyl]-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (4-Methoxy-phenyl)-[(S)-1-phenyl-2-((R)-toluene-4-sulfinyl)-ethyl]-amine(121411-08-3)
• EPA Substance Registry System: (4-Methoxy-phenyl)-[(S)-1-phenyl-2-((R)-toluene-4-sulfinyl)-ethyl]-amine(121411-08-3)

Safety Data

• Hazardous Substances Data: 121411-08-3(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 1613-90-7 4-methoxy-N-[(E)-phenylmethylidene]aniline 
• 104-94-9 4-methoxy-aniline 
• 100-52-7 benzaldehyde 
• 783-08-4 [4-(benzylideneamino)phenyl]methanol 

Downstream Products

• 224433-96-9 [(S)-1-Phenyl-2-((R)-toluene-4-sulfinyl)-ethyl]-carbamic acid benzyl ester 
• 224433-99-2 N-[(S)-1-Phenyl-2-((R)-toluene-4-sulfinyl)-ethyl]-benzamide 
• 116126-04-6 (-)-N-((S)-2-hydroxy-1-phenylethyl)benzamide 
• 20989-17-7 (2S)-2-phenylglycinol 
• 130406-31-4 benzyl (S)-(2-hydroxy-1-phenylethyl)carbamate 
• 224433-92-5 (S)-1-Phenyl-2-((R)-toluene-4-sulfinyl)-ethylamine 

Relevant articles and documents

Asymmetric, Nearly Barrierless C(sp3)-H Activation Promoted by Easily-Accessible N-Protected Aminosulfoxides as New Chiral Ligands

Although chiral sulfoxides are important motifs in medicinal chemistry and asymmetric synthesis, design and applications of sulfoxide ligands are still limited, in particular in the context of asymmetric C-H activation. We disclose herein the conception a

ASYMMETRIC ADDITIONS OF α-SULFOXIDE CARBANION ON IMINES

The formation of the anion of methyl p-tolyl sulfoxide was studied in various experimental conditions.This allowed to get a very good control of diastereoselectivity during addition of the above carbanion on many imines.Various stereoisomerically pure ami