121441-63-2Relevant academic research and scientific papers
Propyne Iminium Salts: Ambifunctional Reactivity towards Sulfur and Nitrogen Nucleophiles
Maas, Gerhard,Wuerthwein, Ernst-Ulrich,Singer, Berndt,Mayer, Theo,Krauss, Detlev
, p. 2311 - 2318 (2007/10/02)
Propyne iminium ions 2a-d have been studied by both ab initio (3-21G//3-21G for 2a) and MNDO calculations (2a-d).It is found that the amino group stabilizes the propargyl cation structure at the expense of the allenyl cation structure.Furthermore, the hig
