121441-79-0Relevant articles and documents
Novel approach to the ansamycin antibiotics macbecin I and herbimycin A. A formal total synthesis of (+)-macbecin I
Martin, Stephen F.,Dodge, Jeffrey A.,Burgess, Laurence E.,Limberakis, Chris,Hartmann, Michael
, p. 3229 - 3246 (2007/10/03)
The asymmetric syntheses of 25 and 29, which constitutes the C(3)-C(15) segment of the stereochemically complex ansa chain of (+)-macbecin I (1) and herbimycin A (2), respectively, have been achieved. The approach features the furan-hydropyranone transfor