121587-37-9

Upstream product

• 143-33-9 sodium cyanide 
• 113337-60-3 (2-Chloromethyl-6-methoxy-phenyl)-trimethyl-silane 

Downstream Products

• 121587-42-6 N-{2-[2-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolane-4-carbonyl)-3-methoxy-phenyl]-ethyl}-2,2,2-trifluoro-acetamide 
• 121587-42-6 N-trifluoroacetyl-2-<2-<(4S,5R)-5-benzyloxymethyl-2,2-dimethyl-1,3-dioxolan-4-carbonyl>-3-methoxyphenyl>ethylamine 
• 121587-41-5 N-(2-{2-[((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-3-methoxy-phenyl}-ethyl)-2,2,2-trifluoro-acetamide 
• 121587-41-5 N-trifluoroacetyl-2-<2-<(4R,5R)-5-benzyloxymethyl-1,3-dioxolan-4-yl>-1-hydroxymethyl-3-methoxyphenyl>ethylamine 
• 157543-62-9 (S)-1-((1S,2S)-3-Benzyloxy-1,2-dihydroxy-propyl)-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 
• 157459-08-0 (R)-benzyl 1-<(1R,2R)-3-benzyloxy-1,2-dihydroxypropyl>-8-methoxy-3,4-dihydro-2(1H)-isoquinolinecarboxylate 
• 159411-83-3 (R)-1-<(4R,5R)-5-benzyloxymethyl-2,2-dimethyl-1,3-dioxolan-4-yl>-8-methoxy-1,2,3,4-tetrahydroisoquinoline 
• 157459-10-4 (S)-1-Formyl-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 
• 157459-09-1 (R)-benzyl 1-formyl-8-methoxy-3,4-dihydro-2(1H)-isoquinolinecarboxylate 
• 121587-44-8 (S)-1-Hydroxymethyl-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 
• 121587-51-7 (R)-benzyl 1-hydroxymethyl-8-methoxy-3,4-dihydro-2(1H)-isoquinolinecarboxylate 
• 159411-84-4 (R)-1-<(1R,2R)-3-benzyloxy-1,2-dihydroxypropyl>-8-methoxy-1,2,3,4-tetrahydroisoquinoline 
• 157543-63-0 (S)-1-((4S,5S)-5-Benzyloxymethyl-2-thioxo-[1,3]dioxolan-4-yl)-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 
• 157459-19-3 (R)-1-((E)-3-Benzyloxy-propenyl)-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 

Relevant academic research and scientific papers

CHIRAL SYNTHESIS OF THE ABE-RING SYSTEM OF QUINOCARCIN

An enantiomeric pair of the ABE-ring systems of quinocarcin (1), a potent antitumor antibiotic, was synthesized in > 95percent ee by employing each enantiomer of 4-O-benzyl-2,3-O-isopropylidene-threose as a chiral auxiliary and featuring novel stereoselective reduction of the 3,4-dihydroisoquinoline derivative.