Tetrahedron Letters p. 6301 - 6304 (1988)
Update date:2022-08-02
Topics:
Saito, Shoichi
Matsuda, Fuyuhiko
Terashima, Shiro
An enantiomeric pair of the ABE-ring systems of quinocarcin (1), a potent antitumor antibiotic, was synthesized in > 95percent ee by employing each enantiomer of 4-O-benzyl-2,3-O-isopropylidene-threose as a chiral auxiliary and featuring novel stereoselective reduction of the 3,4-dihydroisoquinoline derivative.
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