121587-49-3

Upstream product

• 121587-40-4 N-trifluoroacetyl-2-(2-bromo-3-methoxyphenyl)ethylamine 
• 121587-41-5 N-(2-{2-[((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-3-methoxy-phenyl}-ethyl)-2,2,2-trifluoro-acetamide 
• 121587-42-6 N-{2-[2-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolane-4-carbonyl)-3-methoxy-phenyl]-ethyl}-2,2,2-trifluoro-acetamide 
• 157543-62-9 (S)-1-((1S,2S)-3-Benzyloxy-1,2-dihydroxy-propyl)-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 
• 121587-38-0 2-(2-trimethylsilyl-3-methoxyphenyl)ethylamine 
• 113337-60-3 (2-Chloromethyl-6-methoxy-phenyl)-trimethyl-silane 
• 157543-63-0 (S)-1-((4S,5S)-5-Benzyloxymethyl-2-thioxo-[1,3]dioxolan-4-yl)-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 
• 121587-39-1 2,2,2-Trifluoro-N-[2-(3-methoxy-2-trimethylsilanyl-phenyl)-ethyl]-acetamide 
• 121587-37-9 (3-Methoxy-2-trimethylsilanyl-phenyl)-acetonitrile 
• 157459-19-3 (R)-1-((E)-3-Benzyloxy-propenyl)-8-methoxy-3,4-dihydro-1H-isoquinoline-2-carboxylic acid benzyl ester 

Relevant academic research and scientific papers

CHIRAL SYNTHESIS OF THE ABE-RING SYSTEM OF QUINOCARCIN

An enantiomeric pair of the ABE-ring systems of quinocarcin (1), a potent antitumor antibiotic, was synthesized in > 95percent ee by employing each enantiomer of 4-O-benzyl-2,3-O-isopropylidene-threose as a chiral auxiliary and featuring novel stereoselective reduction of the 3,4-dihydroisoquinoline derivative.