121799-15-3Relevant academic research and scientific papers
SEQUENTIAL CLAISEN-ENE APPROACH TO CARBOCYCLIZATION: A NEW ENTRY TO A STEROID C/D RING SYNTHON
Takahashi, Kazuhiko,Mikami, Koichi,Nakai, Takeshi
, p. 5277 - 5280 (1988)
A new and facile entry to a steroid C/D ring synthon is described which relies on the sequential combination of the Claisen rearrangement with the intramolecular ene reaction involving an acetylenic bond with methoxycarbonyl group as the enophile.
