121899-81-8

Basic information

• Product Name: DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH
• Synonyms: DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH;TRIS(2-METHOXYPHENYL)BISMUTH DICHLORIDE
• CAS NO: 121899-81-8
• Molecular Formula: C₂₁H₂₁BiCl₂O₃
• Molecular Weight: 601.28
• Product Categories: New Oxidation of primary & secondary Alcohols;Oxidation;Semimetal Compounds;Synthetic Organic Chemistry;Bi (Bismuth) Compounds;Classes of Metal Compounds;Hypervalent Bismuth Compounds
• Mol File: 121899-81-8.mol

Chemical Properties

• Melting Point: 183 °C(dec.)
• Appearance: /
• Storage Temp.: Refrigerator
• CAS DataBase Reference: DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH(CAS DataBase Reference)
• NIST Chemistry Reference: DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH(121899-81-8)
• EPA Substance Registry System: DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH(121899-81-8)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 121899-81-8(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH is employed as a reagent in organic synthesis reactions, facilitating the formation of complex organic molecules. Its unique structure and properties make it a valuable tool in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Catalysis:
In the field of catalysis, DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH serves as a catalyst to accelerate chemical reactions, enhancing efficiency and selectivity. Its application in catalytic processes is crucial for optimizing reaction pathways and improving the overall yield of desired products.
Used in Antimicrobial Applications:
DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH has been investigated for its potential antimicrobial properties, making it a candidate for use in applications where controlling microbial growth is essential, such as in medical, food preservation, and water treatment industries.
Used in Antitumor Applications:
DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH's antitumor potential is under investigation, suggesting that it could be utilized in oncology for the development of new therapeutic agents targeting various types of cancer. Its application in this field could contribute to the advancement of cancer treatment options.
Used in Chemical Research:
DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH is also used in chemical research to explore its properties and reactions, contributing to the understanding of bismuth chemistry and its applications in various chemical processes.

InChI:InChI=1/3C7H7O.Bi.2ClH/c3*1-8-7-5-3-2-4-6-7;;;/h3*2-5H,1H3;;2*1H/q;;;+2;;/p-2/rC21H21BiCl2O3/c1-25-19-13-7-4-10-16(19)22(23,24,17-11-5-8-14-20(17)26-2)18-12-6-9-15-21(18)27-3/h4-15H,1-3H3

Upstream product

• 578-57-4 2-bromoanisole 
• 193490-01-6 tris(2-methoxyphenyl)(2-oxopropyl)bismuthonium perchlorate 
• 83724-41-8 tris(2-methoxyphenyl)bismuthine 

Downstream Products

• 313973-97-6 [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane 
• 382148-93-8 [(trichloroacetyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane (15)N-labeled 
• 417701-46-3 (mesylimino)tris(2-methoxyphenyl)-λ5-bismuthane 
• 417701-44-1 (tosylimino)tris(2-methoxyphenyl)-λ5-bismuthane 
• 193489-99-5 tetrakis(2-methoxyphenyl)bismuthonium perchlorate 
• 83724-41-8 tris(2-methoxyphenyl)bismuthine 
• 193490-07-2 tetrakis(2-methoxyphenyl)bismuthonium tetrafluoroborate 
• 193490-13-0 tetrakis(2-methoxyphenyl)bismuthonium bromide monohydrate 
• 1415576-80-5 C₂₂H₂₁F₃O₃S 
• 185509-57-3 tris(2-methoxyphenyl)bismuth diacetate 
• 313973-98-7 (CH₃OC₆H₄)3BiNCOC₆H₄NO₂ 
• 233257-05-1 [(trichloroacetyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane 
• 233257-04-0 [(trifluoroacetyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane 
• 313973-99-8 (CH₃OC₆H₄)3BiNCOC₆H₄CN 

Relevant articles and documents

HERBICIDE COMPOSITION

There is provided a herbicidal composition containing a cyclohexanone compound represented by Formula (I) and at least one compound selected from Group A. Group A: consisting of benoxacor, cloquintocet-mexyl, cyometrinil, dichlormid, fenchlorazole-ethyl,

CYCLOHEXANONE COMPOUNDS AND HERBICIDES COMPRISING THE SAME

The present invention provides a compound having an excellent efficacy for controlling weeds. A cyclohexanone compound of the formula (I): wherein m is an integer of 1, 2 or 3; n is an integer of any one of 1 to 5; X represents CH2, O, S, S(O)

Unexpected formation of highly stabilized tetrakis-(2-alkoxyphenyl)bismuthonium salts in the oxidation of tris-(2-alkoxyphenyl)bismuthanes with iodosylbenzene

Treatment of tris-(2-alkoxyphenyl)bismuthanes 1 with iodosylbenzene in methylene dichloride at 40°C led to none of the expected bismuthane oxides 2 but, quite unexpectedly, gave tetrakis-(2-alkoxyphenyl)bismuthonium chlorides 3 in moderate to good yields. In some cases, bismuthonium formates 4 accompanied the main reaction products. Similar treatment in benzene in the presence of benzyl bromide, ethyl bromide, or 2,2,2-trifluoroethyl iodide led to the corresponding bismuthonium bromides 7 and iodides 8. Through anion exchange, a variety of bismuthonium salts including formate 4, tetrafluoroborate 11, toluene-p-sulfonate 12, bromide 7, iodide 8 and perchlorate 13 were prepared from the salt 3 in good yields. In contrast to the known tetraphenylbismuthonium salts, all of these new bismuthonium salts exhibited high thermal stability. The molecular structure of compound 7a was elucidated by X-ray analysis, where the four neighbouring oxygen atoms are found to surround the bismuth atom tetrahedrally via a weak through-space interaction with the metal, making the bismuth centre less susceptible to nucleophilic attack of the halide anion.