121906-80-7Relevant academic research and scientific papers
Chemo- and Stereo-selective Preparation of Cyclopentanone Derivatives from Cyclohexenones using Trimethylstannyl-lithium as a Key Reagent
Sato, Tadashi,Watanabe, Toshiyuki,Hayata, Toshihiro,Tsukui, Tohru
, p. 153 - 154 (2007/10/02)
Upon treatment with trimethylsilyl trifluoromethane-sulphonate, β-stannylcyclohexanones afforded cyclopentanones chemo- and stereo-selectively.
REGIO AND STEREOSELECTIVE PREPARATION OF SUBSTITUTED CYCLOPENTANONES FROM CYCLOHEXENONES UTILIZING TRIMETHYLSTANNYLLITHIUM AS A KEY REAGENT
Sato, Tadashi,Watanabe, Toshiyuki,Hayata, Toshihiro,Tsukui, Toru
, p. 6401 - 6408 (2007/10/02)
3-Stannylcyclohexanones gave cyclopentanones via carbon-skeleton rearrangement with high regio and stereoselectivity, upon treatment with trimethylsilyl trifluoromethanesulfonate.
