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122045-07-2

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122045-07-2 Usage

General Description

"(E)-4,4′-(diazene-1,2-diyl)dibenzonitrile" is a chemical compound with the molecular formula C14H8N4. It is a diazene derivative featuring a dibenzonitrile backbone and is classified as a diarylamine. (E)-4,4′-(diazene-1,2-diyl)dibenzonitrile is a yellow solid that is sparingly soluble in water. It is primarily used as an intermediate in the synthesis of other organic compounds, and it is not known to have any significant commercial or industrial uses on its own. The chemical structure of "(E)-4,4′-(diazene-1,2-diyl)dibenzonitrile" makes it a potentially useful building block for the creation of more complex and functionalized compounds, particularly in the fields of pharmaceuticals and materials science.

Check Digit Verification of cas no

The CAS Registry Mumber 122045-07-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,2,0,4 and 5 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 122045-07:
(8*1)+(7*2)+(6*2)+(5*0)+(4*4)+(3*5)+(2*0)+(1*7)=72
72 % 10 = 2
So 122045-07-2 is a valid CAS Registry Number.

122045-07-2Relevant articles and documents

A Molecular Hybrid of an Atomically Precise Silver Nanocluster and Polyoxometalates for H2 Cleavage into Protons and Electrons

Suzuki, Kosuke,Yamaguchi, Kazuya,Yamazoe, Seiji,Yokogawa, Daisuke,Yonesato, Kentaro

, p. 16994 - 16998 (2021)

Atomically precise silver (Ag) nanoclusters are promising materials as catalysts, photocatalysts, and sensors because of their unique structures and mixed-valence states (Ag+/Ag0). However, their low stability hinders the in-depth st

Electrosynthesis of Azobenzenes Directly from Nitrobenzenes

Ma, Yanfeng,Wu, Shanghui,Jiang, Shuxin,Xiao, Fuhong,Deng, Guo-Jun

, p. 3334 - 3338 (2021/10/29)

The electrochemical reduction strategy of nitrobenzenes is developed. The chemistry occurs under ambient conditions. The protocol uses inert electrodes and the solvent, DMSO, plays a dual role as a reducing agent. Its synthetic value has been demonstrated by the highly efficient synthesis of symmetric, unsymmetric and cyclic azo compounds.

Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters

Yan, Ziqiang,Xie, Xiaoyu,Song, Qun,Ma, Fulei,Sui, Xinyu,Huo, Ziyu,Ma, Mingming

supporting information, p. 1301 - 1307 (2020/03/11)

We report a catalytic tandem reduction of nitroarenes by sodium borohydride (NaBH4) in aqueous solution under ambient conditions, which can selectively produce five categories of nitrogen-containing compounds: anilines, N-aryl hydroxylamines, azoxy-, azo- and hydrazo-compounds. The catalyst is in situ-generated ultrasmall palladium nanoclusters (Pd NCs, diameter of 1.3 ± 0.3 nm) from the reduction of Pd(OAc)2 by NaBH4. These highly active Pd NCs are stabilized by surface-coordinated nitroarenes, which inhibit the further growth and aggregation of Pd NCs. By controlling the concentration of Pd(OAc)2 (0.1-0.5 mol% of nitroarene) and NaBH4, the water/ethanol solvent ratio and the tandem reaction sequence, each of the five categories of N-containing compounds can be obtained with excellent yields (up to 98%) in less than 30 min at room temperature. This tunable catalytic tandem reaction works efficiently with a broad range of nitroarene substrates and offers a green and sustainable method for the rapid and large-scale production of valuable N-containing chemicals.

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