122236-34-4

Upstream product

• 100-52-7 benzaldehyde 
• 114362-79-7 4-(1-hydroxybenzyl)-2-sulfolene 
• 114397-08-9 4-bromo-3-(phenylthio)-2-sulfolene 
• 100-39-0 benzyl bromide 
• 108-98-5 thiophenol 

Relevant academic research and scientific papers

A Facile Synthesis of Stable Precursors to 2-Alkylated-3-(phenylthio)-1,3-butadienes

3-Sulfolenes 3 which are stable precursors to 2-alkylated-3-(phenylthio)-1,3-butadienes (4) are conveniently prepared. Key Words Sulfur-substituted dienes; 3-Sulfolenes.

Convenient Synthesis of 3-- and 3-Alkyl-Substituted 3-Sulfolenes

3--3-sulfolenes (5) were conveniently synthesized by a sequence of mesylation, elimination, and Michael addition reactions of 4-hydroxyalkylated 2-sulfolenes (2), which were prepared regioselectively via ultrasound-promoted allylzincation of 4-bromo-2-sulfolene (1). 3-Alkyl-3-sulfolenes were synthesized from desulfurization of 5.The application of the sequence was exemplified with the simple synthesis of α-myrcene.