122250-08-2Relevant academic research and scientific papers
ASYMMETRIC SYNTHESES VI: ASYMMETRIC ALDOL REACTION OF D-CAMPHOR IMINE DERIVED FROM BENZYLAMINE
Yaozhong, Jiang,Guilan, Liu,Jingen, Deng
, p. 1291 - 1298 (2007/10/02)
Addition of the D-camphor imine of benzylamine to a variety of aldehydes or ketones gives diastereoselectivites ranging from 16-70percent.The d.e. value is attributed by the difference of the orientation of C-11 groups.The rotation of (5e) indicates that addition reaction occurs from the pro-R face of lithium derivative (2).
