63765-03-7

Upstream product

• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 100-46-9 benzylamine 

Downstream Products

• 1306602-63-0 R,R,R-N-benzyl-camphorammonium tris(pentafluorophenyl)hydridoborate 
• 158411-96-2 (1R,2R,4R)-N-benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine 
• 142508-10-9 benzyl-((1R)-bornyl)-amine 
• 174195-97-2 (S)-1-(1'-amino-1'-phenylmethyl)cyclohexanol 
• 122250-04-8 1-{(R)-Phenyl-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-methyl}-cyclohexanol 
• 122250-04-8 1-{(S)-Phenyl-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-methyl}-cyclohexanol 
• 530-36-9 (S)-2-Amino-1,2-diphenyl-ethanol 
• 122250-08-2 (S)-1,2-Diphenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 122250-08-2 (R)-1,2-Diphenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 122250-05-9 (S)-1-(4-Methoxy-phenyl)-2-phenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 122250-05-9 (R)-1-(4-Methoxy-phenyl)-2-phenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 122250-06-0 (S)-1-(3,4-Dimethoxy-phenyl)-2-phenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 122250-06-0 (R)-1-(3,4-Dimethoxy-phenyl)-2-phenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 888-33-5 (S)-1-Amino-1,2-diphenyl-propan-2-ol 

Relevant academic research and scientific papers

Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

Reductions of chiral ketimines effected under H2 by catalytic amounts of B(C6F5)3 result in moderate to excellent diastereoselectivities. In the case of camphor and menthone derived imines, the reductions procee

ASYMMETRIC SYNTHESES IV: ENANTIOSELECTIVE SYNTHESIS OF (R)-BENZYLIC AMINES VIA ALKYLATION OF D-CAMPHOR KETIMINE

An efficient asymmetric synthesis of (R)-benzylic amines in optical purity 36-90percent had been achieved by alkylation of a chiral ketimine prepared from D-camphor and benzylamine.Diastereoselectivity in the alkylation is dependent on the alkyl halides.