122258-63-3Relevant academic research and scientific papers
IODOTRIMETHYLSILANE DEOXYGENATION OF CARBONYL CONJUGATED ALLYLIC ETHERS
Hartman, David A.,Curley, Robert W. Jr.
, p. 645 - 646 (1989)
The attempted demethylation of 4-methoxy-β-ionone (1) with iodotrimethylsilane gave the unexpected product, β-ionone (2).This reagent may prove useful in the cleavage of allylic ethers conjugated to ketones.
A convenient cross-metathesis approach to trisporins
López-Sánchez, Cristóbal,Hernández-Cervantes, Carmen,Rosales, Antonio,álvarez-Corral, Míriam,Mu?oz-Dorado, Manuel,Rodríguez-García, Ignacio
experimental part, p. 9542 - 9549 (2010/02/27)
Three series of trisporins have been prepared using a strategy in which a cross-metathesis is the key step. This reaction has proved to be highly regioselective, allowing the combination of α- or β-ionone derivatives having a 1,1-disustituted olefin with
73. Photochemistry of 5,6-Epoxy-1,3-dienes in the Ionone Series. Influence of a Hydroxy Group in the 7-Position
Goldener, Urs,Scheller, Markus E.,Mathies, Peter,Frei, Bruno,Jeger, Oskar
, p. 635 - 650 (2007/10/02)
The synthesis and photolyses of the epoxydiene (E)-5 are described.On triplet excitation (λ>280 nm, acetone), (E)-5 undergoes initial cleavage of the C(5)-O bond leading to the intermediate c.Presumably an H-shift (c->e) followed by the fragmentation of t
